Consider the C2v molecule OF2; take the molecule to lie in the yz-plane, with z directed along the C2 axis; the mirror plane σ′v is the yz-plane, and σv is the xz-plane. The combination pz(A) + pz(B) of the two F atoms spans A1, and the combination pz(A) − pz(B) of the two F atoms spans B2. Are there any valence orbitals of the central O atom that can have a non-zero overlap with these combinations of F orbitals? How would the situation be different in SF2, where 3d orbitals might be available?
Consider the C2v molecule OF2; take the molecule to lie in the yz-plane, with z directed along the C2 axis; the mirror plane σ′v is the yz-plane, and σv is the xz-plane. The combination pz(A) + pz(B) of the two F atoms spans A1, and the combination pz(A) − pz(B) of the two F atoms spans B2. Are there any valence orbitals of the central O atom that can have a non-zero overlap with these combinations of F orbitals? How would the situation be different in SF2, where 3d orbitals might be available?
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter7: Molecular Structures
Section: Chapter Questions
Problem 65QRT
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Consider the C2v molecule OF2; take the molecule to lie in the yz-plane, with z directed along the C2 axis; the mirror plane σ′v is the yz-plane, and σv is the xz-plane. The combination pz(A) + pz(B) of the two F atoms spans A1, and the combination pz(A) − pz(B) of the two F atoms spans B2. Are there any valence orbitals of the central O atom that can have a non-zero overlap with these combinations of F orbitals? How would the situation be different in SF2, where 3d orbitals might be available?
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