Show the mechanism for each reaction. Determine if the reaction favors products or reactants. Use pkas to calculate the Keq. Add an energy diagram

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Show the mechanism for each reaction. Determine if the reaction favors products or reactants. Use 
pkas to calculate the Keq. Add an energy diagram 

### Reaction Mechanism: Protonation of Acetone

This diagram illustrates the protonation equilibrium of acetone in an aqueous solution. 

**Chemical Reaction Overview:**

1. **Reactants:**
   - **Acetone (CH₃COCH₃):** Shown as a carbonyl group (C=O) bonded to two methyl groups (CH₃).
   - **Hydronium Ion (H₃O⁺):** Illustrated as an oxygen atom bonded to three hydrogen atoms, carrying a positive charge.
   
2. **Equilibrium Reaction:**
   - The reaction proceeds in an equilibrium, as indicated by the double arrows.
   
3. **Products:**
   - **Protonated Acetone:** The carbonyl oxygen of acetone becomes protonated, forming a positively charged complex.
   - **Water (H₂O):** A byproduct of the proton transfer from H₃O⁺.

**Mechanistic Insight:**

- **Proton Transfer:** The hydronium ion donates a proton to the carbonyl oxygen of acetone, resulting in a positively charged oxygen in the product. This represents a classic example of a proton transfer (Brønsted-Lowry acid-base reaction).

This reaction is fundamental in understanding acid catalysis in organic reactions. It is commonly studied in the context of keto-enol tautomerism and is crucial in various biochemical pathways.
Transcribed Image Text:### Reaction Mechanism: Protonation of Acetone This diagram illustrates the protonation equilibrium of acetone in an aqueous solution. **Chemical Reaction Overview:** 1. **Reactants:** - **Acetone (CH₃COCH₃):** Shown as a carbonyl group (C=O) bonded to two methyl groups (CH₃). - **Hydronium Ion (H₃O⁺):** Illustrated as an oxygen atom bonded to three hydrogen atoms, carrying a positive charge. 2. **Equilibrium Reaction:** - The reaction proceeds in an equilibrium, as indicated by the double arrows. 3. **Products:** - **Protonated Acetone:** The carbonyl oxygen of acetone becomes protonated, forming a positively charged complex. - **Water (H₂O):** A byproduct of the proton transfer from H₃O⁺. **Mechanistic Insight:** - **Proton Transfer:** The hydronium ion donates a proton to the carbonyl oxygen of acetone, resulting in a positively charged oxygen in the product. This represents a classic example of a proton transfer (Brønsted-Lowry acid-base reaction). This reaction is fundamental in understanding acid catalysis in organic reactions. It is commonly studied in the context of keto-enol tautomerism and is crucial in various biochemical pathways.
Expert Solution
Step 1: Explain the principle involved

Whether equilibrium lies on the right side or left side depends upon the acidity of the reactant and product.  

If reactant is more acidic than product,  then equilibrium lies completely on the the right side. If product is more acidic than reactant then the equilibrium lies on left side.  

The indicator for acidity is pka- value.     lower the pka value , higher will be the acidity.  

So, we can say if reactant has lower pka value than product,  then equilibrium lies on right side.      

While if product has lower pKa  value than reactant,  then equilibrium lies completely on the right side. If product is more acidic than reactant then equilibrium lies on left side.


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