Show that ар MoreAmode (of (1) эт منوع A nodgo RT2. = -H

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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**Title: Thermodynamic Derivation**

**Objective:**

Show that:

\[ \left( \frac{\partial (\ln\gamma)}{\partial T} \right)_P = \frac{-H}{RT^2} \]

**Explanation:**

In this derivation, we aim to prove the relationship between the change in the natural logarithm of the activity coefficient (\(\gamma\)) with respect to temperature at constant pressure, and the enthalpy (\(H\)) divided by the product of the gas constant (\(R\)) and the square of the temperature (\(T^2\)).

This relationship can be derived from fundamental thermodynamic principles and is essential in understanding the temperature dependence of chemical activity, which plays a critical role in various fields such as chemical engineering, physical chemistry, and thermodynamics.
Transcribed Image Text:**Title: Thermodynamic Derivation** **Objective:** Show that: \[ \left( \frac{\partial (\ln\gamma)}{\partial T} \right)_P = \frac{-H}{RT^2} \] **Explanation:** In this derivation, we aim to prove the relationship between the change in the natural logarithm of the activity coefficient (\(\gamma\)) with respect to temperature at constant pressure, and the enthalpy (\(H\)) divided by the product of the gas constant (\(R\)) and the square of the temperature (\(T^2\)). This relationship can be derived from fundamental thermodynamic principles and is essential in understanding the temperature dependence of chemical activity, which plays a critical role in various fields such as chemical engineering, physical chemistry, and thermodynamics.
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