Selected bond dissociation enthalpies are given in this table. is made by addition polymerization of vinyl chloride (C2 H3 Cl). Vinyl chloride is synthesized from ethylene (C2H4) in a two-step process involving the following equilibria: Dissociation enthalpy (kJ/mol) Bond • Equilibrium 1: C2 H4(g) + Cl2 (g) = C2H4C12 (g) Equilibrium 2: C2 H4 Cl2 (g) = C2 H3 Cl(g) + HC1(g) C-C 348 C=C 614 C=C 839 Part A C-C1 328 С-Н 413 What are the C-C bond orders in C2 H4 Cl2 and C2H3 Cl, respectively? Cl–Cl 242 Express your answers numerically separated by commas. H-H 436 • View Available Hint(s) H-C1 431

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Polyvinyl chloride (PVC) is one of the most commercially important polymers. PVC
is made by addition polymerization of vinyl chloride (C2H3 Cl). Vinyl chloride is
synthesized from ethylene (C2 H4) in a two-step process involving the following
equilibria:
Selected bond dissociation enthalpies are given in
this table.
Dissociation enthalpy
Bond
Equilibrium 1: C2H4(g) + Cl2 (g) = C2H¾C12 (g)
Equilibrium 2: C2H4 Cl2 (g) = C2H3 Cl(g) + HC1(g)
(kJ/mol)
C-C
348
C=C
614
C=C
839
Part A
C-C1
328
C-H
413
What are the C-C bond orders in C2H4C12 and C2H3 Cl, respectively?
Cl-Cl
242
Express your answers numerically separated by commas.
Н-Н
436
• View Available Hint(s)
Н-СІ
431
Transcribed Image Text:Polyvinyl chloride (PVC) is one of the most commercially important polymers. PVC is made by addition polymerization of vinyl chloride (C2H3 Cl). Vinyl chloride is synthesized from ethylene (C2 H4) in a two-step process involving the following equilibria: Selected bond dissociation enthalpies are given in this table. Dissociation enthalpy Bond Equilibrium 1: C2H4(g) + Cl2 (g) = C2H¾C12 (g) Equilibrium 2: C2H4 Cl2 (g) = C2H3 Cl(g) + HC1(g) (kJ/mol) C-C 348 C=C 614 C=C 839 Part A C-C1 328 C-H 413 What are the C-C bond orders in C2H4C12 and C2H3 Cl, respectively? Cl-Cl 242 Express your answers numerically separated by commas. Н-Н 436 • View Available Hint(s) Н-СІ 431
Part D
Suppose that the synthesis of C2H3 Cl from C2H4 was carried out in the two-compartment reactor shown. The synthesis of C2H4Cl2 takes place in the left compartment,
followed by the synthesis of C2 H3 Cl in the right compartment. Indicate how the two compartments should be designed to maximize the yield of the vinyl chloride.
Reactants
Products
To separation, recycling,
and recovery units
Equilibrium 1
Recycle
unreacted
Equilibrium 2
Drag each time to the appropriate bin.
• View Available Hint(s)
Reset
Help
should be refrigerated.
should be heated.
should be larger in volume.
should be smaller in volume.
The left compartment...
The right compartment..
Pearson
Transcribed Image Text:Part D Suppose that the synthesis of C2H3 Cl from C2H4 was carried out in the two-compartment reactor shown. The synthesis of C2H4Cl2 takes place in the left compartment, followed by the synthesis of C2 H3 Cl in the right compartment. Indicate how the two compartments should be designed to maximize the yield of the vinyl chloride. Reactants Products To separation, recycling, and recovery units Equilibrium 1 Recycle unreacted Equilibrium 2 Drag each time to the appropriate bin. • View Available Hint(s) Reset Help should be refrigerated. should be heated. should be larger in volume. should be smaller in volume. The left compartment... The right compartment.. Pearson
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