Select the correct statements about atomic and ionic sizes below. Check all that CIis smaller than Cl + Na is smaller than Na* 3+ Au* is smaller than Au³ 02- is smaller than S- Mg-+ is smaller than Als+ 3+ + Aust is smaller than Au" Als+ is smaller than Mg* Na* is smaller than Na Cl is smaller than Cl¯ s?- is smaller than O?-

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Exercise: Identifying Correct Statements on Atomic and Ionic Sizes

Please select the correct statements regarding the comparative sizes of atoms and ions from the options below. Check all that apply.

- [ ] Cl⁻ is smaller than Cl
- [ ] Na is smaller than Na⁺
- [ ] Au⁺ is smaller than Au³⁺
- [ ] O²⁻ is smaller than S²⁻
- [ ] Mg²⁺ is smaller than Al³⁺
- [ ] Au³⁺ is smaller than Au⁺
- [ ] Al³⁺ is smaller than Mg²⁺
- [ ] Na⁺ is smaller than Na
- [x] Cl is smaller than Cl⁻
- [ ] S²⁻ is smaller than O²⁻

### Explanation of Concepts

- **Ionic Radius vs. Atomic Radius**: Anions (negatively charged ions) are generally larger than their neutral atoms, while cations (positively charged ions) are smaller than their neutral atoms. This occurs because the addition of electrons in anions increases electron-electron repulsion, while the removal of electrons in cations decreases it, allowing the atomic nucleus to pull the remaining electrons closer.

- **Comparison of Ionic Sizes with Different Charges**: For ions with the same number of electrons (isoelectronic), a higher positive charge results in a smaller ion due to increased nuclear attraction for electrons. Conversely, a higher negative charge usually leads to a larger ion.
Transcribed Image Text:### Exercise: Identifying Correct Statements on Atomic and Ionic Sizes Please select the correct statements regarding the comparative sizes of atoms and ions from the options below. Check all that apply. - [ ] Cl⁻ is smaller than Cl - [ ] Na is smaller than Na⁺ - [ ] Au⁺ is smaller than Au³⁺ - [ ] O²⁻ is smaller than S²⁻ - [ ] Mg²⁺ is smaller than Al³⁺ - [ ] Au³⁺ is smaller than Au⁺ - [ ] Al³⁺ is smaller than Mg²⁺ - [ ] Na⁺ is smaller than Na - [x] Cl is smaller than Cl⁻ - [ ] S²⁻ is smaller than O²⁻ ### Explanation of Concepts - **Ionic Radius vs. Atomic Radius**: Anions (negatively charged ions) are generally larger than their neutral atoms, while cations (positively charged ions) are smaller than their neutral atoms. This occurs because the addition of electrons in anions increases electron-electron repulsion, while the removal of electrons in cations decreases it, allowing the atomic nucleus to pull the remaining electrons closer. - **Comparison of Ionic Sizes with Different Charges**: For ions with the same number of electrons (isoelectronic), a higher positive charge results in a smaller ion due to increased nuclear attraction for electrons. Conversely, a higher negative charge usually leads to a larger ion.
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