Homework Help is Here – Start Your Trial Now!
Science
Chemistry
S. t. 1. NaNH2 2. CH3Br Cl₂ (excess) 1. NaNH2 2. Br

S. t. 1. NaNH2 2. CH3Br Cl₂ (excess) 1. NaNH2 2. Br

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

Draw the major product to each of the following reactions.

### Chemical Reactions with Alkyne Compounds Below are detailed descriptions and representations of reactions involving alkynes: #### Reaction r. **Reactants:** - An alkyne with a propargyl group is treated sequentially with: 1. Sodium amide (NaNH₂). 2. Methyl bromide (CH₃Br). **Chemical Transformation:** - Step 1: Sodium amide deprotonates the terminal alkyne, creating a nucleophilic acetylide ion. - Step 2: The acetylide ion then attacks the methyl bromide, resulting in an alkylation reaction that forms a new alkyne. **Diagram:** ``` ≡ | 1. NaNH₂ ≡––– → 2. CH₃Br | ``` #### Reaction s. **Reactants:** - An alkyne with an isopropyl group is treated with excess chlorine (Cl₂). **Chemical Transformation:** - The reaction proceeds through a halogenation process where the excess chlorine reacts with the alkyne, leading to the addition of chlorine atoms across the triple bond until it is fully saturated. **Diagram:** ``` ≡ Cl₂ (excess) | → ≡––– | ``` #### Reaction t. **Reactants:** - An alkyne with an isopropyl group is treated sequentially with: 1. Sodium amide (NaNH₂). 2. Ethyl bromide (C₂H₅Br). **Chemical Transformation:** - Step 1: Sodium amide deprotonates the terminal alkyne, creating a nucleophilic acetylide ion. - Step 2: The acetylide ion then attacks the ethyl bromide, resulting in an alkylation reaction that forms a new alkyne. **Diagram:** ``` ≡ | 1. NaNH₂ ≡––– → 2. C₂H₅Br | ``` These transformations demonstrate the versatility of alkyne compounds in organic synthesis, particularly the creation of more complex molecules through alkylation and halogenation reactions.
Transcribed Image Text:### Chemical Reactions with Alkyne Compounds Below are detailed descriptions and representations of reactions involving alkynes: #### Reaction r. **Reactants:** - An alkyne with a propargyl group is treated sequentially with: 1. Sodium amide (NaNH₂). 2. Methyl bromide (CH₃Br). **Chemical Transformation:** - Step 1: Sodium amide deprotonates the terminal alkyne, creating a nucleophilic acetylide ion. - Step 2: The acetylide ion then attacks the methyl bromide, resulting in an alkylation reaction that forms a new alkyne. **Diagram:** ``` ≡ | 1. NaNH₂ ≡––– → 2. CH₃Br | ``` #### Reaction s. **Reactants:** - An alkyne with an isopropyl group is treated with excess chlorine (Cl₂). **Chemical Transformation:** - The reaction proceeds through a halogenation process where the excess chlorine reacts with the alkyne, leading to the addition of chlorine atoms across the triple bond until it is fully saturated. **Diagram:** ``` ≡ Cl₂ (excess) | → ≡––– | ``` #### Reaction t. **Reactants:** - An alkyne with an isopropyl group is treated sequentially with: 1. Sodium amide (NaNH₂). 2. Ethyl bromide (C₂H₅Br). **Chemical Transformation:** - Step 1: Sodium amide deprotonates the terminal alkyne, creating a nucleophilic acetylide ion. - Step 2: The acetylide ion then attacks the ethyl bromide, resulting in an alkylation reaction that forms a new alkyne. **Diagram:** ``` ≡ | 1. NaNH₂ ≡––– → 2. C₂H₅Br | ``` These transformations demonstrate the versatility of alkyne compounds in organic synthesis, particularly the creation of more complex molecules through alkylation and halogenation reactions.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 1 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Representations of Organic Compounds
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS