(e) The Sn1 displacement 2-bromo-2-methylhexane by sodium iso-propoxide ((CH;)2CH-OʻNª*) on or by soidum butyrate (CH3(CH2)2CO0'Na*).

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(e) The S<sub>N</sub>1 displacement on 2-bromo-2-methylhexane by sodium iso-propoxide ((CH<sub>3</sub>)<sub>2</sub>CH-O<sup>-</sup>Na<sup>+</sup>) or by sodium butyrate (CH<sub>3</sub>(CH<sub>2</sub>)<sub>2</sub>COO<sup>-</sup>Na<sup>+</sup>).
Transcribed Image Text:(e) The S<sub>N</sub>1 displacement on 2-bromo-2-methylhexane by sodium iso-propoxide ((CH<sub>3</sub>)<sub>2</sub>CH-O<sup>-</sup>Na<sup>+</sup>) or by sodium butyrate (CH<sub>3</sub>(CH<sub>2</sub>)<sub>2</sub>COO<sup>-</sup>Na<sup>+</sup>).
Which reaction in each of the following pairs would you expect to be faster?

(i) Write both reactions using bond-line presentation and, using arrows, provide a mechanistic explanation of the course of the reaction. Draw either a transition state or an intermediate product of the reaction;

(ii) Shortly (one sentence) explain your reasoning why one of the two reactions will be faster.
Transcribed Image Text:Which reaction in each of the following pairs would you expect to be faster? (i) Write both reactions using bond-line presentation and, using arrows, provide a mechanistic explanation of the course of the reaction. Draw either a transition state or an intermediate product of the reaction; (ii) Shortly (one sentence) explain your reasoning why one of the two reactions will be faster.
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Sn1 is unimolecular substitution reaction.

 

 

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