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S CHE 375 Problem set 3: 1.)" When oxygens hold a) Determine the number Raman active vibrations Propose assignments of H I.... 010 H b) Determine the number active vibrations of trans reduce & assign). Hint 1: Assume all atoms

S CHE 375 Problem set 3: 1.)" When oxygens hold a) Determine the number Raman active vibrations Propose assignments of H I.... 010 H b) Determine the number active vibrations of trans reduce & assign). Hint 1: Assume all atoms

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Solve 1b!! 5 CHE 375 Problem set 3: Point groups and vibrational spectroscopy Due: 09/24/21. 1.)" When oxygens hold hands..." a) Determine the number and Mulliken symbols of irreducible representations of all IR and Raman active vibrations of cis-H₂O2. Show your work (determine T, then reduce & assign). Propose assignments of the vibrational modes by drawing arrows. H C2 C₂ A B E 1 1 1 -1 Linear functions, Rotations z, R₂ x, y, Rx, Ry Quadratic functions x², y², z², xy yz, xz b) Determine the number and Mulliken symbols of irreducible representations of all IR and Raman active vibrations of trans-H₂O₂. Show your work (determine the point group, determine I, then reduce & assign). Hint 1: Assume all atoms fall into one single plane.
Transcribed Image Text:Solve 1b!! 5 CHE 375 Problem set 3: Point groups and vibrational spectroscopy Due: 09/24/21. 1.)" When oxygens hold hands..." a) Determine the number and Mulliken symbols of irreducible representations of all IR and Raman active vibrations of cis-H₂O2. Show your work (determine T, then reduce & assign). Propose assignments of the vibrational modes by drawing arrows. H C2 C₂ A B E 1 1 1 -1 Linear functions, Rotations z, R₂ x, y, Rx, Ry Quadratic functions x², y², z², xy yz, xz b) Determine the number and Mulliken symbols of irreducible representations of all IR and Raman active vibrations of trans-H₂O₂. Show your work (determine the point group, determine I, then reduce & assign). Hint 1: Assume all atoms fall into one single plane.
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