rotation is possible around sigma bonds but not around pi bonds because pi bonds are always made from hybridized orbitals pi bonds are stronger and resist rotation sigma bonds occur above and below the internuclear axis while pi bonds are only along the internal axis or sigma bonds maintain orbital overlap during rotation while rotation would break orbital overlap between pi orbitals
rotation is possible around sigma bonds but not around pi bonds because pi bonds are always made from hybridized orbitals pi bonds are stronger and resist rotation sigma bonds occur above and below the internuclear axis while pi bonds are only along the internal axis or sigma bonds maintain orbital overlap during rotation while rotation would break orbital overlap between pi orbitals
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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rotation is possible around sigma bonds but not around pi bonds because
pi bonds are always made from hybridized orbitals
pi bonds are stronger and resist rotation
sigma bonds occur above and below the internuclear axis while pi bonds are only along the internal axis
or
sigma bonds maintain orbital overlap during rotation while rotation would break orbital overlap between pi orbitals
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