In compounds that contain more than two atoms, it is common to refer to the orbitals so that each atom is prepared to make bonds in the observed geometry. geometries with a hybridization label. This label refers a mixing of atomic Geometry Linear Hybridization Orbitals Bonding 20 sp Cartoon 2 sp-orbitals 2 p-orbitals Trigonal Planar sp2 3 sp²-orbitals 1 p-orbitals 3 o 1 T Tetrahedral sp3 4 sp-orbitals 0 p-orbitals 4 o Trigonal sp°d 5 sp°d -orbitals 4 d-orbital 5 o Bipyramidal* 0-4 T Octahedral* sp³d? 6 sp°d?-orbitals 3 d-orbitals 0-3 T * There are exceptions to this table but these are the examples we will use. How many orbitals does each atom have? • Does that match the number of orbitals in its valence shell? Does the number of orbitals match the number of bonds? • Label the pictures of the orbitals in the table above with the type of bond each can make. • Draw a picture of two sp? carbons forming ethene (CH2CH2) with 4 hydrogen atoms. Draw a picture of a carbon forming methane (CH4) with 4 hydrogen atoms. • Draw a picture of two sp carbons forming ethyne (HCCH).
In compounds that contain more than two atoms, it is common to refer to the orbitals so that each atom is prepared to make bonds in the observed geometry. geometries with a hybridization label. This label refers a mixing of atomic Geometry Linear Hybridization Orbitals Bonding 20 sp Cartoon 2 sp-orbitals 2 p-orbitals Trigonal Planar sp2 3 sp²-orbitals 1 p-orbitals 3 o 1 T Tetrahedral sp3 4 sp-orbitals 0 p-orbitals 4 o Trigonal sp°d 5 sp°d -orbitals 4 d-orbital 5 o Bipyramidal* 0-4 T Octahedral* sp³d? 6 sp°d?-orbitals 3 d-orbitals 0-3 T * There are exceptions to this table but these are the examples we will use. How many orbitals does each atom have? • Does that match the number of orbitals in its valence shell? Does the number of orbitals match the number of bonds? • Label the pictures of the orbitals in the table above with the type of bond each can make. • Draw a picture of two sp? carbons forming ethene (CH2CH2) with 4 hydrogen atoms. Draw a picture of a carbon forming methane (CH4) with 4 hydrogen atoms. • Draw a picture of two sp carbons forming ethyne (HCCH).
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter10: Molecular Structure And Bonding Theories
Section: Chapter Questions
Problem 10.99QE: The molecular orbital diagram of NO shown in Figure 10.47 also applies to the following species....
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