رجوع > ↑ 41 من 58 3.8. By pK, measurements it can be shown that 1,1,1-bicyclopentanecarboxylic acid is 10 times more acidic than 2,2-dimethylpropanoic acid, even though both have a quaternary carbon attached to the carboxylic acid group. Account for this difference in pk. CO₂H pk, 4.09 LLI-bicyclopentanecarboxylic acid CO₂H H₂C CHICH, pk, 5.09 2.2-dimethylpropanoic acid Problems CHEM mechanism 03/12/21 3:00

Chemistry
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41 من 58
3.8. By pK, measurements it can be shown that 1,1,1-bicyclopentanecarboxylic
acid is 10 times more acidic than 2,2-dimethylpropanoic acid, even though
both have a quaternary carbon attached to the carboxylic acid group.
Account for this difference in pk.
CO₂H
pk, 4.09
LLI-bicyclopentanecarboxylic acid
CO₂H
H₂C CHICH,
pk, 5.09
2.2-dimethylpropanoic acid
Problems CHEM mechanism
03/12/21
3:00
Transcribed Image Text:رجوع > ↑ 41 من 58 3.8. By pK, measurements it can be shown that 1,1,1-bicyclopentanecarboxylic acid is 10 times more acidic than 2,2-dimethylpropanoic acid, even though both have a quaternary carbon attached to the carboxylic acid group. Account for this difference in pk. CO₂H pk, 4.09 LLI-bicyclopentanecarboxylic acid CO₂H H₂C CHICH, pk, 5.09 2.2-dimethylpropanoic acid Problems CHEM mechanism 03/12/21 3:00
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