Results & Discussion All reactions were endothermic (Table 1), but the enthalpies deviated from known values. The temperature change that occurred in each trial was used to calculate the enthalpy change, which was used to calculate the enthalpy per mole (Table 1). The q value for each trials could be used to predict the enthalpy of the joined reaction as shown below: dH = mc dT Equation 1 where AH, is the enthalpy of the combined reaction, AHsol is the enthalpy of dissolving of sodium hydroxide, and AHneut is the enthalpy of neutralization of sodium hydroxide and hydrochloric acid. The AH, calculated from Equation 1 was 11% different than the measured AHr. Table 1: Experimentally determined heats of reaction PROCESS AT AH AHRN Solution 3.90 -1640 -3.30 x 104 Neutralization 5.90 -2530 -5.05 x 10* Reaction 10.5 -4530 -9.35 x 104 The percent difference shows our results were not accurate. This is due to expoerimental error. One source of error could have been that the balance we used to find the mass of the solution was not properly calibrated. The thermometers could also have been old. Finally, it is possible that the solid Sodium Hydroxide used in the experiment sucked in water from the air, causing the molecules to breakdown.
Results & Discussion All reactions were endothermic (Table 1), but the enthalpies deviated from known values. The temperature change that occurred in each trial was used to calculate the enthalpy change, which was used to calculate the enthalpy per mole (Table 1). The q value for each trials could be used to predict the enthalpy of the joined reaction as shown below: dH = mc dT Equation 1 where AH, is the enthalpy of the combined reaction, AHsol is the enthalpy of dissolving of sodium hydroxide, and AHneut is the enthalpy of neutralization of sodium hydroxide and hydrochloric acid. The AH, calculated from Equation 1 was 11% different than the measured AHr. Table 1: Experimentally determined heats of reaction PROCESS AT AH AHRN Solution 3.90 -1640 -3.30 x 104 Neutralization 5.90 -2530 -5.05 x 10* Reaction 10.5 -4530 -9.35 x 104 The percent difference shows our results were not accurate. This is due to expoerimental error. One source of error could have been that the balance we used to find the mass of the solution was not properly calibrated. The thermometers could also have been old. Finally, it is possible that the solid Sodium Hydroxide used in the experiment sucked in water from the air, causing the molecules to breakdown.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
100%
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY