The value of enthalpy for a chemical reaction, A;H, can be experimentally determined by measuring the value of the equilibrium constant of a reaction at different temperatures. Tc do this we need to plot the natural log of the equilibrium constant, In(Keq) (your y- variable), vs 1/T (your x-variable) where T is the temperature in Kelvin. The slope of this plot = -A,H/R where R is the gas constant 8.314 J/(K · mole). In an experiment, the following values of equilibrium constant were determined at the specified temperatures in Kelvin: %3D T(K) 350 400 450 500 Keg(no units) 0.000398 0.0141 0.186 1.48 Make a plot of In(Keq) (y-axis) versus 1/T (x-axis). You will need to set up extra columns in your spreadsheet for 1/T and In(Keq) using formulas. Using the linear trendline feature of Google Sheets, determine the value of the slope (include units!). Also enter the formula for calculating slope and intercept into cells. From these cells, calculate A,H using spreadsheet calculations. Keep track of units and significant figures! [Note: You do not need to understand thermodynamics to do this exercise.l
The value of enthalpy for a chemical reaction, A;H, can be experimentally determined by measuring the value of the equilibrium constant of a reaction at different temperatures. Tc do this we need to plot the natural log of the equilibrium constant, In(Keq) (your y- variable), vs 1/T (your x-variable) where T is the temperature in Kelvin. The slope of this plot = -A,H/R where R is the gas constant 8.314 J/(K · mole). In an experiment, the following values of equilibrium constant were determined at the specified temperatures in Kelvin: %3D T(K) 350 400 450 500 Keg(no units) 0.000398 0.0141 0.186 1.48 Make a plot of In(Keq) (y-axis) versus 1/T (x-axis). You will need to set up extra columns in your spreadsheet for 1/T and In(Keq) using formulas. Using the linear trendline feature of Google Sheets, determine the value of the slope (include units!). Also enter the formula for calculating slope and intercept into cells. From these cells, calculate A,H using spreadsheet calculations. Keep track of units and significant figures! [Note: You do not need to understand thermodynamics to do this exercise.l
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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