Recall from Section 7.9 that most ketones and aldehydes exist primarily in their keto form, as shown in Table 7-1. Propanedial, however, exists primarily (>99%) in its enol form. Explain why. Hint: Examine its structure in the enol form. H H. Propanedial TABLE 7-1 Relative Percentages of Keto and Enol Forms Tautomerization Reaction Percent Keto Form Percent Enol Form 99.99994% 0.00006% 99.986% 0.014% 99.9999995% 0.0000005% H. 99.9999988% 0.0000012% H H. 99.99996% 0.00004%

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Recall from Section 7.9 that most ketones and aldehydes exist primarily in their keto form,
as shown in Table 7-1. Propanedial, however, exists primarily (>99%) in its enol form.
Explain why. Hint: Examine its structure in the enol form.
H
H.
Propanedial
Transcribed Image Text:Recall from Section 7.9 that most ketones and aldehydes exist primarily in their keto form, as shown in Table 7-1. Propanedial, however, exists primarily (>99%) in its enol form. Explain why. Hint: Examine its structure in the enol form. H H. Propanedial
TABLE 7-1 Relative Percentages of Keto and Enol Forms
Tautomerization Reaction
Percent Keto Form
Percent Enol Form
99.99994%
0.00006%
99.986%
0.014%
99.9999995%
0.0000005%
H.
99.9999988%
0.0000012%
H
H.
99.99996%
0.00004%
Transcribed Image Text:TABLE 7-1 Relative Percentages of Keto and Enol Forms Tautomerization Reaction Percent Keto Form Percent Enol Form 99.99994% 0.00006% 99.986% 0.014% 99.9999995% 0.0000005% H. 99.9999988% 0.0000012% H H. 99.99996% 0.00004%
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