Question 5 [20 marks] (a) [10 marks] The general reaction between a thiocyanate ion and a sulfonium ion is given below: NCS R₁S* NCS-R + R₂S For the following thiomolecules, explain which atom is attacked by NCS- and why. (b) [6 marks] S Provide the product of the following reaction. Draw the mechanism and explain the regiospecific outcome. SnCl4 CI (c) [4 marks] Discuss how the compound shown below will react with HCI. NH2 N-H Page 6 of 16

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Question 5 [20 marks]
(a) [10 marks]
The general reaction between a thiocyanate ion and a sulfonium ion is given below:
NCS
R₁S*
NCS-R + R₂S
For the following thiomolecules, explain which atom is attacked by NCS- and why.
(b)
[6 marks]
S
Provide the product of the following reaction. Draw the mechanism and explain the
regiospecific outcome.
SnCl4
CI
(c) [4 marks]
Discuss how the compound shown below will react with HCI.
NH2
N-H
Page 6 of 16
Transcribed Image Text:Question 5 [20 marks] (a) [10 marks] The general reaction between a thiocyanate ion and a sulfonium ion is given below: NCS R₁S* NCS-R + R₂S For the following thiomolecules, explain which atom is attacked by NCS- and why. (b) [6 marks] S Provide the product of the following reaction. Draw the mechanism and explain the regiospecific outcome. SnCl4 CI (c) [4 marks] Discuss how the compound shown below will react with HCI. NH2 N-H Page 6 of 16
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