Question 26Predict the FINAL (?) product (or a mixture of products) for the following synthetic transformation:two diastereomersNaSHDMSOBrSN2t-BuOK1. OsO42. H₂O2?Br2Hofmann productН2Pd catalysttwo diastereomersABCD20 2020 20ABCD

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Answered: Question 26 Predict the FINAL (?)…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter9: Alkynes: An Introduction To Organic Synthesis

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Problem 46AP: A hydrocarbon of unknown structure has the formula C8H10. On catalytic hydrogenation over the...

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Question 29 Predict the FINAL (?) product (or a mixture of products) for the following synthetic transformation: two diastereomers Br NASH DMSO Br SN2 1. OsO4 2. H₂O2 t-BuOK ? Br2 Hofmann product ? H₂ Pd catalyst two diastereomers B C D Br Br Br ABCD OA ов ОС OD Br Br
A hydrocarbon of unknown structure has the formula C8H10. On catalytic hydrogenation over the Lindlar catalyst, 1 equivalent of Î—2 is absorbed. On hydrogenation overa palladium catalyst, 3 equivalents of Î—2 are absorbed. (a) How many degrees of unsaturation are present in the unknown structure? (b) How many triple bonds are Present? (c) How many double bonds are present? (d) How many rings are present? (e) Draw a structure that fits the data.
Aa.132.
a) What are the major organic products of the following reactions? OCEN A HCI, H20 1. LDA Br2 В 2. CH3CH2BR hv b) CH3 KMNO4, H* CH3-C=CH-CH3 Hot
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Question 17 Predict the FINAL (?) product (or a mixture of products) for the following synthetic transformation: two enantiomers 1) PhMgCl 2) H₂O 1.03 2. Me₂S ? .CI 1) NaNH, (excess) 2) H₂O H2SO4, H₂O HgSO4 1) n-BuLi 2) Br CI منه ABCD 000 ов OD B 0 H2 Lindlar's catalyst D
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26. What would be the major organic product for the following reaction? -O Na + ? Br -OH a) b) racemic 27. What would be the major substitution product for the following reaction? a) HO ■CI CH3 ??? c) d) 28. What would be the major organic product for the following reaction? a) Br NaF DMSO ? b). c) d) e) 29. What would be the major organic product for the following reaction? Br CHS Na+ ? DMSO a) S b) S c) ༠༤། d) racemic racemic racemic 30. What would be the major elimination product for the following reaction? CH3 CH3OH CI ??? CH3 CH3 a) b) ос c) " OCH 3 e) OCH 3 racemic
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5. Draw the organic products formed in the following reactions. az vo 2169 snol mo 40-60 g a. b. N [1] LIAIH4 [2] H₂O odior hobnod noitibbs, ogrob [1] Mg Br [2] Å quore [3] H3O+ C. O OH Isprie [1] TBDMS-Cl, imidazole [2] CH3Li [3] H₂O [Indicate stereochemistry.] quong griynol is dit bruggmos lynddisa vesi tuontiv d. of enousNaBH42 OCH3 CH3OH

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Question 26 Predict the FINAL (?) product (or a mixture of products) for the following synthetic transformation: two diastereomers NaSH DMSO Br SN2 t-BuOK 1. OsO4 2. H₂O2 ? Br2 Hofmann product Н2 Pd catalyst two diastereomers A B C D 20 2020 20 A B C D