Question 25 A proposed mechanism for the Br-catalyzed aqueous reaction is shown below. Br H+ + HNO₂ + C6H5NH₂ CH₂N₂ + 2H₂O H + HNO₂H₂N₂ rapid equilib. H₂NO₂ + Br¯ONBr + H₂O slow ONBr + CH3NH₂CH₂N₂ + H₂O + Br¯ fast Apply steady-state approximiation to answer the following questions. Write the letter of your answer. What is the rate of the intermediates? A. 0 B. 1 Which of the following corresponds to the rate of ONBr? A.k. [H₂NO₂+] B.k₂ [H₂NO₂+][Br] C.k[ONBr][CH₂NH₂] Given the following expression for the rate of H₂NO₂*, what is the rate constant for each term? X[H+ [HNO₂]-Y[H₂NO₂+]-Z[H₂NO₂+][Br] Use the following choices. A. K₁ B.K.1 C. K2 D.K3 X- Y= Z-

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Question 25
A proposed mechanism for the Br-catalyzed aqueous reaction is shown below.
Br
H+ + HNO₂ + C6H5NH₂
CH₂N₂ + 2H₂O
k₂
H+ + HNO₂ H₂NO
rapid equilib.
k-1
H₂NO+BONBr + H₂O
slow
ONBr + CH3NH₂CH₂N₂ + H₂O + Br¯
fast
Apply steady-state approximiation to answer the following questions. Write the letter of your answer.
What is the rate of the intermediates?
A. 0
B. 1
Which of the following corresponds to the rate of ONBr?
A.k. [H₂NO₂+]
B.k₂ [H₂NO₂+][Br]
C.* [ONBr][C.H_NH,]
k.
Given the following expression for the rate of H₂NO₂*, what is the rate constant for each term?
X[H+][HNO₂]-Y[H₂NO₂+]-Z[H₂NO₂+][Br]
Use the following choices.
A. K₁
B.K.1
C. K₂
D. k3
X =
Y =
Z=
Transcribed Image Text:Question 25 A proposed mechanism for the Br-catalyzed aqueous reaction is shown below. Br H+ + HNO₂ + C6H5NH₂ CH₂N₂ + 2H₂O k₂ H+ + HNO₂ H₂NO rapid equilib. k-1 H₂NO+BONBr + H₂O slow ONBr + CH3NH₂CH₂N₂ + H₂O + Br¯ fast Apply steady-state approximiation to answer the following questions. Write the letter of your answer. What is the rate of the intermediates? A. 0 B. 1 Which of the following corresponds to the rate of ONBr? A.k. [H₂NO₂+] B.k₂ [H₂NO₂+][Br] C.* [ONBr][C.H_NH,] k. Given the following expression for the rate of H₂NO₂*, what is the rate constant for each term? X[H+][HNO₂]-Y[H₂NO₂+]-Z[H₂NO₂+][Br] Use the following choices. A. K₁ B.K.1 C. K₂ D. k3 X = Y = Z=
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