Question 19Predict the expected product for each reaction and provide IUPAC name for the correct starting material to yield the desired epoxide:OH°1NAMEABс2H2SO4?EtOHDEto,OHOEtНо,HOEtOHO.EtOBox 1 (name):Box 2:

Answered: Question 19 Predict the expected…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 64AP: The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold...

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Question 19 Predict the expected product for each reaction and provide IUPAC name for the correct starting material to yield the desired epoxide: OH 2 1 CI H₂SO4 NAME ? EtOH A B C D Eto, OH OEt Но, HO. EtO HO. EtO Box 1 (name): Box 2:
4. Give the starting alkene and any other reagents needed to selectively make the following compounds (with no organic byproducts!): OH L Eto OH all OH Br Br Br
Identify the suitable reagents for the given reaction and arrange them accordingly. 1 OH OEt 2 OEt OEt O 1) EtOH, H₂SO4; 2) EtOH, H₂SO4 O 1) EtONa followed by H₂O; 2) TsCl/py followed by EtONa O 1) EtONa followed by H₂O; 2) NaH followed by EtBr O 1) EtOH, H₂SO4; 2) NaH followed by EtBr O 1) EtOH, H₂SO4; 2) TsCy followed by EtONa
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Choose the reaction conditions to complete the acid-base reaction shown
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Answer the following questions from the reaction given below: OH OH 1) BH3-THF 2) NAOH/H2O2 OH C a) What is the major product(s) of the reaction (A-D) ? b) What is the mechanism by which the major product is formed ? c) Is the reaction Regioselective ? Explain DI A.
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Identify the suitable reagents for the given reaction and arrange them accordingly. OH A+&+F OEt 1 2 OEt OEt 1) EtOH, H₂SO4; 2) EtOH, H₂SO4 1) EtONa followed by H₂O; 2) TsCl/py followed by EtONa 1) EtONa followed by H₂O; 2) NaH followed by EtBr O 1) EtOH, H₂SO4; 2) NaH followed by EtBr O 1) EtOH, H₂SO4; 2) TsCmy followed by EtONa
Reaction with which of the following compounds in an acetylide reaction would lengthen the carbon chain by one carbon and add a primary alcohol? O ethanal O formaldehyde О ерохide O acetone O carbonic acid QUESTION 4 The reagent/reaction of choice for this reduction is || HC-CH=CH-CH2CH2CH2 CO2H CH2OH-CH=CH-CH2CH2CH2 CO2H O lithium aluminum hydride O potassium permanganate O sodium borohydride O Grignard reaction O SN2 reaction
OH Give Keagent A) HBv (aq) 3) HBr in ether c) Br SOBrz, Pyridine D) NBS Brz
13) In the following reaction, identify the major product. OH KHSO4 OH A C. OH E 14) When 2,2-dibromobutane is treated with 3 moles of NaNH2, NH3 followed by water, what the major organic product? A) 1-bromo2-butyne B) 1-butyne C) 2-butyne D) 1-bromo-1-butyne E) 1-butene

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Question 19 Predict the expected product for each reaction and provide IUPAC name for the correct starting material to yield the desired epoxide: OH ° 1 NAME A B с 2 H2SO4 ? EtOH D Eto, OH OEt Но, HO EtO HO. EtO Box 1 (name): Box 2: