Question 18 Provide the reagents necessary to carry out the following conversion H O 1.03: 2. Zn/acetic acid O 1. H2O/ H2SO4 2. PCC/CH2C12 O 1.9-BBN; 2. H202/N2OH/H2O; 3. Cro3/H2SO4/H20 O 1.9-BBN: 2. H202/N2OH/H20 O 1. PCC/ CH2Cl2
Question 18 Provide the reagents necessary to carry out the following conversion H O 1.03: 2. Zn/acetic acid O 1. H2O/ H2SO4 2. PCC/CH2C12 O 1.9-BBN; 2. H202/N2OH/H2O; 3. Cro3/H2SO4/H20 O 1.9-BBN: 2. H202/N2OH/H20 O 1. PCC/ CH2Cl2
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Question 18**
**Objective:** Determine the reagents necessary to carry out the following organic conversion.
**Diagram:**
- **Left Structure:** A straight chain alkene with a triple bond (alkyne) positioned along the chain.
- **Right Structure:** A straight chain aldehyde with a carbon-oxygen double bond (carbonyl group) at the end of the chain.
**Options:**
1. **Option 1:**
- Step 1: O₃
- Step 2: Zn/acetic acid
2. **Option 2:**
- Step 1: H₂O/H₂SO₄
- Step 2: PCC/CH₂Cl₂
3. **Option 3:**
- Step 1: 9-BBN
- Step 2: H₂O₂/NaOH/H₂O
- Step 3: CrO₃/H₂SO₄/H₂O
4. **Option 4:**
- Step 1: 9-BBN
- Step 2: H₂O₂/NaOH/H₂O
5. **Option 5:**
- Step 1: PCC/CH₂Cl₂
**Graph Explanation:**
The reaction involves converting a carbon-carbon triple bond (alkyne) into a carbon-oxygen double bond (aldehyde). This type of reaction often involves oxidation and hydration steps, which are reflected in the potential reagent choices.
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