Question 1 (a) Distinguish between the differential rate law and the integrated rate law. Which of these is often called just the "rate law"? What is half-life of first order reaction?

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Chapter1: Chemical Foundations
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Question 1 (a) Distinguish between the differential rate law and the integrated rate
law. Which of these is often called just the "rate law"? What is half-life of
first order reaction?
(b) The rate of the reaction;
O(g) + NO2 (g) NO(g) + O2(g) was studied at a certain tem-
perature.
1) In one experiment, NO2 was in large excess, at a concentration of 1.0
x 1013 molecules/cm3 with the following data collected:
Time (s)
(atoms/cm)
5.0 x 10
1.0 x 10-
1.9 x 10
2.0 x 10
6.8 x 10
3.0 x 10-
2.5 x 10
What is the order of the reaction with respect to oxygen atoms?
ii). The reaction is known to be first order with respect to NO2. De-
termine the
11
alue of t
anstant
Transcribed Image Text:Question 1 (a) Distinguish between the differential rate law and the integrated rate law. Which of these is often called just the "rate law"? What is half-life of first order reaction? (b) The rate of the reaction; O(g) + NO2 (g) NO(g) + O2(g) was studied at a certain tem- perature. 1) In one experiment, NO2 was in large excess, at a concentration of 1.0 x 1013 molecules/cm3 with the following data collected: Time (s) (atoms/cm) 5.0 x 10 1.0 x 10- 1.9 x 10 2.0 x 10 6.8 x 10 3.0 x 10- 2.5 x 10 What is the order of the reaction with respect to oxygen atoms? ii). The reaction is known to be first order with respect to NO2. De- termine the 11 alue of t anstant
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