Question 1 (a) Distinguish between the differential rate law and the integrated rate law. Which of these is often called just the "rate law"? What is half-life of first order reaction?

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Question 1 (a) Distinguish between the differential rate law and the integrated rate
law. Which of these is often called just the "rate law"? What is half-life of
first order reaction?
(b) The rate of the reaction;
O(g) + NO: (g) - NO(g) + O:(g) was studied at a certain tem-
perature.
i) In one experiment, NO, was in large excess, at a concentration of 1.0
x 1013 molecules/cm with the following data collected:
Time ( latomaiem)
50 x 10
1.0x 10
20 x
19x 10
68 x 10
25x 10
30 x 10
What is the order of the reaction with respect to oxygen atoms?
ii). The reaction is known to be first order with respect to NO,. De-
termine the
overall rate law and the value of the rate constant.
Transcribed Image Text:Question 1 (a) Distinguish between the differential rate law and the integrated rate law. Which of these is often called just the "rate law"? What is half-life of first order reaction? (b) The rate of the reaction; O(g) + NO: (g) - NO(g) + O:(g) was studied at a certain tem- perature. i) In one experiment, NO, was in large excess, at a concentration of 1.0 x 1013 molecules/cm with the following data collected: Time ( latomaiem) 50 x 10 1.0x 10 20 x 19x 10 68 x 10 25x 10 30 x 10 What is the order of the reaction with respect to oxygen atoms? ii). The reaction is known to be first order with respect to NO,. De- termine the overall rate law and the value of the rate constant.
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