QUESTION 1 a) Define rate of reaction. Write the expression to show the relationship between the rate of disappearance of mercury(II) chloride, HgCl2 and the rate of formation of mercury(1) chloride, Hg2Cl2. 2H9CI2 (aq) + C2O42- (aq) → 2CI-(aq) + 2CO2 (g) + Hg2Cl2 (s) b) Calculate the activation energy, Ea (in J mol1) of a reaction occurring at 679 K given that the forward reaction has a rate constant, k of 7.8 s-1 and Arrhenius constant, A of 16.3 s-1. State the effect on the Ea value when temperature is increased. The gas constant, R is 8.314 J mol-1 K-1.

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Chapter1: Chemical Foundations
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QUESTION 1
a) Define rate of reaction. Write the expression to show the relationship between the rate of
disappearance of mercury(II) chloride, HgCl2 and the rate of formation of mercury(1)
chloride, Hg2Cl2.
2HgCl2 (aq) + C2042- (aq) → 2CI-(aq) + 2CO2 (g) + Hg2Cl2 (s)
b) Calculate the activation energy, Ea (in J mol-1) of a reaction occurring at 679 K given that
the forward reaction has a rate constant, k of 7.8 s-1 and Arrhenius constant, A of
16.3 s-1. State the effect on the Ea value when temperature is increased. The gas
constant, R is 8.314 J mol-1 K-1.
Transcribed Image Text:QUESTION 1 a) Define rate of reaction. Write the expression to show the relationship between the rate of disappearance of mercury(II) chloride, HgCl2 and the rate of formation of mercury(1) chloride, Hg2Cl2. 2HgCl2 (aq) + C2042- (aq) → 2CI-(aq) + 2CO2 (g) + Hg2Cl2 (s) b) Calculate the activation energy, Ea (in J mol-1) of a reaction occurring at 679 K given that the forward reaction has a rate constant, k of 7.8 s-1 and Arrhenius constant, A of 16.3 s-1. State the effect on the Ea value when temperature is increased. The gas constant, R is 8.314 J mol-1 K-1.
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