Classes Of Functional Groups
Organic Chemistry deals mostly with carbon and hydrogens, also called hydrocarbons, but those groups which replace hydrogen and bonds with carbon to give a characteristic nature, unique of their own, to the hydrocarbon they are attached to, are called functional groups. All the compounds belonging to a functional group undergo reactions in a similar pattern and are known to have similar physical and chemical properties.
Characteristics Of Functional Groups
In organic chemistry, we encounter a number of special substituent groups which are attached to the hydrocarbon backbone. These groups impart certain characteristics to the molecule of which it is a part of and thus, become the highlight of that particular molecule.
IUPAC Nomenclature
In Chemistry, IUPAC stands for International Union of Pure and Applied Chemistry which suggested a systematic naming approach for the organic and inorganic compounds, as in the beginning stage of nomenclature one single chemical compound was named in many ways by which lead to confusion. The need for this approach aroused as the number of chemical compounds newly discovered were increasing (approximately 32 million compounds) and the basic concept of nomenclature i.e. the trivial nomenclature and the derived system of nomenclature failed to overcome the challenge. It is an important task to name a chemical compound systematically and unambiguously which reduces lots of confusion about the newly reported compounds.
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Q1: Determine the R/S configuration of the chirality center in following compound.
Q2:- Match the statement in the left column with the best concept from the right colum
Stereoisomers with an asymmetric carbon center and non-superimposable mirror
H3C
Images
Equal amounts of two enantiomers
Isomers that differ in connections between atoms
Achiral molecule that has chiral centers.
H-O:
HH
Q3:- follow the flow of electrons indicated by the curved arrows in each of the following polar reactions, and predic
products that result.
CH3
?
CH(CH3)2
CH₂OH
H
H&C
a-meso compound
H3C-C
H₂C
CN
b-diasteromers
CHÍNH
c-constitutional isomers
Q4:- Give IUPAC names for the following compound..
Q5:- Draw structure corresponding to the following IUPAC name: 2-Methyl-1,5-hexadiene
Q6:- Calculate the degree of unsaturation in each of the following formulas.2 points: (a) C₁0H12N2O3
Q7:- Assign E or Z configuration to the double bond in the following compound.
1
d-racemic mixture
e- enantiomers
OCH3
CH3CHCH₂CH3
CH₂CH₂CH₂CH=CHCHCH₂CH3
(b) C₂0](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0156783f-9e76-4938-b581-1738d025e07e%2F210800f5-877f-403c-91c8-05f00f1eed6f%2Fnv4uof7_processed.jpeg&w=3840&q=75)
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