Q. VI: An equimolar liquid mixture of benzene and toluene is separated into two product streams by distillation. At each point in the column some of the liquid vaporizes and some of the vapor stream condenses. The vapor leaving the top of the column, which contains 97 mole% benzene, is completely condensed and split into two equal fractions: one is taken off as the overhead product stream, and the other (the reflux) is recycled to the top of the column. The overhead product stream contains 89.2% of the benzene fed to the column. The liquid leaving the bottom of the column is fed to a partial reboiler in which 45% of it is vaporized. The vapor generated in the reboiler (the boilup) is recycled to become the rising vapor stream in the column, and the residual reboiler liquid is taken off as the bottom product stream. The compositions of the streams leaving the reboiler are governed by the relation, YB/(1 - YB) XB/(1 - XB) = 2.25 where YB and XB are the mole fractions of benzene in the vapor and liquid streams, respectively. 1) Take a basis of 100 moles fed to the column. Draw and completely label a flowchart, and for each of system/sub-system (overall process, column, total condenser, and partial reboiler), do the degree-of-freedom analysis. 2) Write in order the equations you would solve to determine all unknown variables on the flowchart, circling the variable for which you would solve in each equation. 3) Calculate the molar amounts of the overhead and bottoms products, the mole fraction of benzene in the bottoms product, and the percentage recovery of toluene in the bottoms product (100 x moles toluene in bottoms/mole toluene in feed).

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Q. VI: An equimolar liquid mixture of benzene and toluene is separated into two product streams
by distillation. At each point in the column some of the liquid vaporizes and some of the vapor
stream condenses. The vapor leaving the top of the column, which contains 97 mole% benzene,
is completely condensed and split into two equal fractions: one is taken off as the overhead
product stream, and the other (the reflux) is recycled to the top of the column. The overhead
product stream contains 89.2% of the benzene fed to the column. The liquid leaving the bottom
of the column is fed to a partial reboiler in which 45% of it is vaporized. The vapor generated in
the reboiler (the boilup) is recycled to become the rising vapor stream in the column, and the
residual reboiler liquid is taken off as the bottom product stream. The compositions of the streams
leaving the reboiler are governed by the relation,
YB/(1 - YB)
XB/(1 - XB)
= 2.25
where YB and XB are the mole fractions of benzene in the vapor and liquid streams, respectively.
1) Take a basis of 100 moles fed to the column. Draw and completely label a flowchart, and for
each of system/sub-system (overall process, column, total condenser, and partial reboiler), do the
degree-of-freedom analysis.
2) Write in order the equations you would solve to determine all unknown variables on the
flowchart, circling the variable for which you would solve in each equation.
3) Calculate the molar amounts of the overhead and bottoms products, the mole fraction of
benzene in the bottoms product, and the percentage recovery of toluene in the bottoms product
(100 x moles toluene in bottoms/mole toluene in feed).
Transcribed Image Text:Q. VI: An equimolar liquid mixture of benzene and toluene is separated into two product streams by distillation. At each point in the column some of the liquid vaporizes and some of the vapor stream condenses. The vapor leaving the top of the column, which contains 97 mole% benzene, is completely condensed and split into two equal fractions: one is taken off as the overhead product stream, and the other (the reflux) is recycled to the top of the column. The overhead product stream contains 89.2% of the benzene fed to the column. The liquid leaving the bottom of the column is fed to a partial reboiler in which 45% of it is vaporized. The vapor generated in the reboiler (the boilup) is recycled to become the rising vapor stream in the column, and the residual reboiler liquid is taken off as the bottom product stream. The compositions of the streams leaving the reboiler are governed by the relation, YB/(1 - YB) XB/(1 - XB) = 2.25 where YB and XB are the mole fractions of benzene in the vapor and liquid streams, respectively. 1) Take a basis of 100 moles fed to the column. Draw and completely label a flowchart, and for each of system/sub-system (overall process, column, total condenser, and partial reboiler), do the degree-of-freedom analysis. 2) Write in order the equations you would solve to determine all unknown variables on the flowchart, circling the variable for which you would solve in each equation. 3) Calculate the molar amounts of the overhead and bottoms products, the mole fraction of benzene in the bottoms product, and the percentage recovery of toluene in the bottoms product (100 x moles toluene in bottoms/mole toluene in feed).
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