Q 7: An electronic system with 12 л-electrons (all of them in conjugation) can be treated as a particle in a 2-D box of size of 3 Å x 6 Å. Calculate the wavelength corresponding to the lowest energy electronic transition for this system. The expression for the energy of a 2-D box with sides of length a and b is h² (n² Enxny=8me + where nx and ny are quantum numbers (1, 2, 3, 4, etc.). These two quantum numbers are independent of each other and do not have to be equal, though they will be equal for some energy levels, for example the lowest energy state (the ground state) is E11. Some of the energy levels will degenerate.

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Q 7: An electronic system with 12 -electrons (all of them in conjugation) can be treated as a
particle in a 2-D box of size of 3 Å x 6 Å. Calculate the wavelength corresponding to the lowest
energy electronic transition for this system.
The expression for the energy of a 2-D box with sides of length a and b is
(n²
Enginy= 2²2 (22/2+
a²
+
n²
b²
where nx and ny are quantum numbers (1, 2, 3, 4, etc.). These two quantum numbers are independent
of each other and do not have to be equal, though they will be equal for some energy levels, for
example the lowest energy state (the ground state) is E11. Some of the energy levels will degenerate.
Transcribed Image Text:Q 7: An electronic system with 12 -electrons (all of them in conjugation) can be treated as a particle in a 2-D box of size of 3 Å x 6 Å. Calculate the wavelength corresponding to the lowest energy electronic transition for this system. The expression for the energy of a 2-D box with sides of length a and b is (n² Enginy= 2²2 (22/2+ a² + n² b² where nx and ny are quantum numbers (1, 2, 3, 4, etc.). These two quantum numbers are independent of each other and do not have to be equal, though they will be equal for some energy levels, for example the lowest energy state (the ground state) is E11. Some of the energy levels will degenerate.
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