Q 7: An electronic system with 12 л-electrons (all of them in conjugation) can be treated as a particle in a 2-D box of size of 3 Å x 6 Å. Calculate the wavelength corresponding to the lowest energy electronic transition for this system. The expression for the energy of a 2-D box with sides of length a and b is h² (n² Enxny=8me + where nx and ny are quantum numbers (1, 2, 3, 4, etc.). These two quantum numbers are independent of each other and do not have to be equal, though they will be equal for some energy levels, for example the lowest energy state (the ground state) is E11. Some of the energy levels will degenerate.
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- An electron is in a 3p state in the hydrogen atom, given that the expectation value is 12.5a_0 What is the probability of finding the electron within +/- a_0 of your expectation value. (That is, in the range (r − a_0) < r < (r+a_0) where r is the expectation value from above. The answer should be 0.1991.A block is pushed upwards by the horizontal force F, without friction, on a surface inclined to 30° degrees horizontally as shown in the figure. If F = 50 N and m = 3.0 kg, what is the magnitude of the acceleration of the block? Option 3 4.6 m/s² Option 1 Option 2 Option 4 2.9 m/s? Option 5 2.3 m/s? 9.5 m/s? 4.8 m/s?If you have 14 electrons, what are their quantum numbers if the electrons are placed in a cube with length L? How about if the electrons are placed in a hydrogen-like atom? Answer:
- -2r/rB dr. Find the probability that the r2e The radial probabiliity density for an electron in the 1s orbital is given by P(r) electron is found between 1.22 rg and (1.22+0.001)r;. Give you answer to two decimal places in exponential notation. Round your answer to 2 decimal places. Add your answerQ(3): Answer bv (True or False) 1. X-ray have very short wavelengths than the light wavelengths and as a result, its energy is much lower than that of visible light. 2. Ionic solids easily dissociated into its ions in molten state and show high electrical conductivity. while ionic solids are anisotropic and brittle linked with very strong force of interactions. 3. Most Bravais lattices are of the type of primitive unit cell. 4. The axial relationship of a rhombohedral crystal system is given as (a = b = c). 5. There are two rotational operation symmetry of equilateral traingle? 6. The d-spacing of various plane provides information about the structure of the crystal. 7. The force of attraction between atoms or ions is minimum at equilibrium distance (r = r.). 8. X-ray have a very short positive wavelength that lies in the range of 1 angstrom.10
- 17. A particle is in a state (x) = Nex, where N is a constant. What should be the value of N so that the particle is found in the region [0, 1] with probability equal to ½. B) E) ---/2 SE 1 √1-e-2 1 1+e-2 C) ₁-4-2 1-e 18. The quantum state of Hydrogen atom is given below, where subscripts are the values of n, 1, and m. What is the expectation value of the z-component of angular momentum (in units of h) in this given state? (r.6, 4) =(2100 +4210 + √24211 + √321-1) D) - 10 $100 10 125 E)--- LIS4.a. Show that the most probable value of r ( H-atom radius) in la state is a. b: Write wavefunction of the 2s orbital W2,(r,0.6).A quantum simple harmonic oscillator consists of an electron bound by a restoring force proportional to its position relative to a certain equilibrium point. The proportionality constant is 8.79 N/m. What is the longest wavelength of light that can excite the oscillator? nm
- A 12C16O moleule rotates in an XY plane resulting in a moment of inertia = 3.38e-46 kg.m2. What would the energy of the second excited state be? (It is indicated that the answer is 6.45e-4eV but I do not know how to find that valus)A quantum system has a ground state with energy Eo = 0 meV and a 2-fold degenerate excited state with energy E₁ = 50 meV. E1 Calculate the probability of finding the system in its ground state when it is at T = 300 K. Select one: O a. 0.78 O b. 0.22 O c. 1 O d. 0.872-d particle in a box problem. Benzene can be treated as a 2-d box with sides of length 3.5 Å and containing 6 7-electrons. What wavelength of light would be required to promote an electron from the ground state to the first excited electronic state? Answer 135 nm Hint: Use the result for the energy of a particle in a 2-d box: 7²h? Y + (5.1) Nx,Ny 2me L? L3 1,2, 3... and те 9.8 × 10-31kg You need with ng = 1,2, 3... and ny the first 3 energy levels for the 6e¯, and the transition energy will be the energy between the HOMO and the LUMO (the 4th energy level).