Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt= 41°C. Reversible melting experiments indicate thatat TmAHm=37.7 kJ mol-1. Calculate:A. The entropy of melting, ASm-B. The Gibbs free energy of melting, AGm-C. Does the membrane become more or less ordered upon melting?D. There are 32 rotatable CH2CH2 bonds in each molecule that can rotate more freely if themembrane melts. What is the increase in multiplicity on melting a mole of bonds?

We have a phospholipid membrane that "melts" at Tm = 41 C = 314K. Reversible melting experiments…

Answered: Pure membranes of dipalmitoyl lecithin…

College Physics

1st Edition

ISBN:9781938168000

Author:Paul Peter Urone, Roger Hinrichs

Publisher:Paul Peter Urone, Roger Hinrichs

Chapter15: Thermodynamics

Section: Chapter Questions

Problem 63PE: (a) Construct a table showing the macro states and all of the individual microstates for tossing 13...

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6. We used the constant volume heat capacity, Cv, when we talked about thermodynamic cycles. It acts as a proportionality constant between energy and temperature: dU = C₁dT. You can also define a heat capacity for constant pressure processes, Cp. You can think of enthalpy playing a similar role to energy, but for constant pressure processes δαρ C = (37) - Sup Ср ат P = ат Starting from the definition of enthalpy, H = U + PV, find the relationship between Cy and Cp for an ideal gas.
(a) If tossing 100 coins, how many ways (microstates) are there to get me three most likely macro states of 49 heads and 51 tails, 50 heads and 50 tails, and 51 heads and 49 tails? (b) What percent of the total possibilities is this? (Consult Table 15.4.)
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A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P21.65). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state, (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally, (f) Find Q, W, and Eint for each of the processes, (g) For the whole cycle A B C A, find Q, W, and Eint.
(a) What is the gauge pressure in a 25.0 cc car tire containing 3.60 mol of gas in a 30.0-L volume? (b) What will its gauge pressure be if you add 1.00 L of gas originally at atmospheric pressure and 25.0 ? Assume the temperature remains at 25.0 cc and the volume remains constant.
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