Provide explanations for the number of intense perchlorate Cl-O stretching vibrational modes observed in the IR of the following three silver(I) complexes.  explain briefly  1) The perchlorate anion in Ag(NH3)2(ClO4) has a single intense Cl-O stretching   vibrational mode observed by IR at 1170cm-1.  2) The IR of   Ag(NH3)ClO4 has three Cl-O  stretching vibrational modes at 1220 cm-1,1130 cm-1and 920 cm-1 observed in the IR .

Q: Determine the CFSE in terms of A. and P for the following complexes: W a) [Fe(CN)6]4 b) [Ru(NH3)6]³+…

A: The objective of the question is to determine the Crystal Field Stabilization Energy (CFSE) for the…

Q: Explain why the complex [Fe(H2O)6]3+ has Do = 14,000 cm-1, while [Fe(H2O)6]2+ has Do = 9,350 cm-1.

A:

Q: NH NH, NH, Terpyridyl (terpy) Bisethylenetriamine (tris) How do you expect these molecules to…

A: Denticity refers to the number of donor groups in a single ligand that bind to a central atom in a…

Q: Let’s consider octahedral Sc3+ and Ti3+ complexes.  How many d electrons will each have? Sc3+: 0;…

A: How many d electrons will each have? Sc3+ and Ti3+

Q: The energy of the absorption band in the electronic spectrum of the  [Ti(H2O)6]3+   complex is 20300…

A: Stability of a complex can be explained by CFSE i.e. crystal field stabilisation energy. For this…

Q: 6. KCo[Fe(CN)6] has an unusually low-energy charge transfer band at 550 nm. When this compound is…

A:

Q: At 580 nm, the wavelength of maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of…

A:

Q: (a) [Cr(II)(H2O)6]2+ and [Cr(III)(H2O)6]3+ display markedly different ligand exchange rates. Which…

A: Introduction : We have to study about ligand for these type of questions .

Q: The correct statement is…. Crystal field strength at [PtCl4]2- > [Pt(NH3)4]2+ Crystal field strength…

A: Crystal field strength of 5th period transition metal is more than 4rth period transition metal and…

Q: Predicting color and magnetic properties from a crystal field theory ener... 0/5 Izabella 2+ When a…

A: Step 1:

Q: Compare the ligand field strengths of CO and Cl, in terms of the types of bonds in which they can be…

A: CO is Sigma donor and pi acceptor ligand while Cl is only Sigma donor ligand .thus there type of…

Q: Account for any differences in the number of unpaired electrons between [Co(H2O)6](BF4)2and…

A: There are two types of ligands that cause the splitting of d-orbitals of the metal ion. These are…

Q: 2- :O: 2- Oxalate ion Carbonate ion How would you expect these ions to function as a ligand? O It…

A: Both of the ions have available lone pain electron through which they form bonding with metal , so…

Q: For [Fe(CN)6]*, please write the valence electron configuration of the metal ion, the ground- state…

A: In the given complex, iron is the central metal atom which is present in +2 oxidation state. The…

Q: What is the structure of [Co(NH3)5Cl]Cl₂? Draw it, include the correct geometry. Be sure to indicate…

A: The IUPAC name of the complex is - Pentaamminechlorocobalt(lll) chloride. It is a red-violet…

Q: Provide the name of the coordination complex Na[CoCl4(NH3)2] b) Calculate the orbital multiplicity…

A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…

Q: Most Zn2+complexes are colorless.

A:

Q: Which two structural features vary between the "deformational" isomers of [Ir2(dimen)4]2+? Group of…

A: To determine the two structural features that vary between the deformational isomers of…

Q: a) Draw the lewis structure of the nitrate ion and discuss its potential to serve as an ambidentate…

A: Ambidentate Ligand : This are one type of monodentate ligands having two different donar atoms, that…

Q: When the Ti3+ ion is complexed by ligands X (a neutral molecule) and Y (an anion) it gives…

A: Octahedral species have 6 ligands that come towards central metal atom then, there is d orbital…

Q: [CrCl6]3-has a maximum in its visible absorption spectrum at 735 nm. Calculate its crystal field…

A: The objective of the question is to calculate the crystal field splitting energy for the complex…

Q: Suppose that you want to determine whether a ligand X is a weak-field or strong-field ligand. Would…

A: Strong field ligand are able to pair the electrons while weak field ligand are not able to pair…

Q: 7. State hapticity of C6H6 and C5H5 ligands in the following complex. Assume total number of valence…

A: The concept of Organometallic Chemistry is used Electron count by neutral electron count…

Organometallic compounds of d-block elements

The transition metals can form complexes since they have vacant d orbitals. They are also termed Coordination compounds. The organometallic compounds of the transition metals could be used as catalysts as well as reagents. For example, organocadmium, organozinc, organocopper, Grignard are used as the reagents for several reactions. Most of the complexes of organo transition metals are used as catalysts for many organic transformation reactions.