Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Curved Arrow Mechanism for the Reaction**
**Description:**
The reaction involves converting a cyclobutanol compound to a chlorocyclobutane using hydrochloric acid (HCl).
**Mechanism Steps:**
1. **Reactants:**
- A cyclobutanol (a four-membered ring with an -OH group attached).
- Hydrochloric acid (HCl).
2. **Reaction:**
- The -OH group in cyclobutanol will be converted into a better leaving group by reacting with HCl.
- HCl provides a proton (H+) to the -OH group, forming water (a good leaving group) and a carbocation at the carbon.
- The chloride ion (Cl-) from HCl then attacks the carbocation, forming the chlorocyclobutane product.
3. **Products:**
- Chlorocyclobutane (a four-membered ring with a Cl group attached).
**Additional Notes:**
- The reaction is typical of hydrohalogenation, in which alcohols are converted to alkyl halides using hydrogens with halides (like HCl).
- Curved arrows are used to illustrate the movement of electron pairs, showing:
- The donation of a lone pair from the oxygen in -OH to the H+ from HCl.
- The departure of water as a leaving group.
- The attack of Cl- on the carbocation.
**Interactive Section:**
- Users can visualize how the electrons move through a series of curved arrows in a simulated diagram.
**Upload Section:**
- For additional resources, users can upload files related to their educational or laboratory experiments.
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