Propose a structure that is consistent with each of the following ¹H NMR spectra. In each case, the molecular formula is provided. For spectra with numbers at the bottom of the signal you will need to determine the integration, others with numbers above the signal integration has been determined for you. 1. Proton NMR CgH100 9 8 13.9 T 21.5 Proton NMR C5H12O Proton NMR C5H1002 5.0 3. 6.33 7 6 Integration Values 5 4 3 14.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0.6 0.4 ppm Integration Values 13.6 27.8 84.5 41.9 2. 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 Integration Values 19.4 37.9 2 1 ppm 0.5 ppm 20.9

EBK A SMALL SCALE APPROACH TO ORGANIC L
4th Edition
ISBN:9781305446021
Author:Lampman
Publisher:Lampman
Chapter95: Nuclear Magnetic Resonance Spectroscopy (proton Nmr)
Section: Chapter Questions
Problem 1P
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Propose a structure that is consistent with each of the following ¹H NMR spectra. In each case, the
molecular formula is provided. For spectra with numbers at the bottom of the signal you will need to
determine the integration, others with numbers above the signal integration has been determined for you.
1.
2.
Proton NMR
C₂H100
9
8
13.9 T
21.5
Proton NMR
C5H12O
Proton NMR
C5H1002
5.0
3. 6.33
4.5
7
4.0
6
5
Integration Values
3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8
Integration Values 13.6
27.8 84.5 41.9
4
3
14.2
3.5 3.0 2.5 2.0 1.5 1.0
Integration Values 19.4
37.9
2
1 ppm
0.5 ppm
20.9
0.6 0.4 ppm
Transcribed Image Text:Propose a structure that is consistent with each of the following ¹H NMR spectra. In each case, the molecular formula is provided. For spectra with numbers at the bottom of the signal you will need to determine the integration, others with numbers above the signal integration has been determined for you. 1. 2. Proton NMR C₂H100 9 8 13.9 T 21.5 Proton NMR C5H12O Proton NMR C5H1002 5.0 3. 6.33 4.5 7 4.0 6 5 Integration Values 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 Integration Values 13.6 27.8 84.5 41.9 4 3 14.2 3.5 3.0 2.5 2.0 1.5 1.0 Integration Values 19.4 37.9 2 1 ppm 0.5 ppm 20.9 0.6 0.4 ppm
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