Propose a feasable synthesis of the target molecule (TM, Fig. 1) from the indicated starting material (SM). The proposal should contain: retrosynthetic analysis that includes general transformations; • forward synthesis that aligns with retrosynthetic plan and includes all reagents needed to ac- complish each transformation; • curved arrow mechanism of one of the steps. ОН SM TM Figure 1: Synthetic target

Propose a feasable synthesis of the target molecule (TM, Fig. 1) from the indicated starting material (SM). The proposal should contain: retrosynthetic analysis that includes general transformations; • forward synthesis that aligns with retrosynthetic plan and includes all reagents needed to ac- complish each transformation; • curved arrow mechanism of one of the steps. ОН SM TM Figure 1: Synthetic target

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter19: Eas: Electrophilic Aromatic Substitution

Section: Chapter Questions

Problem 11CTQ

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Select the keyword or phrase that will best complete each sentence. Key terms: backside carbocation elimination frontside hyperconjugation inversion maintenance nucleophile product racemization stronger substitution weaker Alkyl halides undergo A orbital. reactions with Brønsted-Lowry bases. is a sp² hybridized and trigonal planar and contains a vacant p All SN2 reactions proceed with in attack of the nucleophile, resulting of configuration at a stereognic center. Spreading out charge by the overlap of an empty p orbital with an adjacent o bond is called Equilibrium favors the products of nucleophilic substitution when the leaving group is a base than the nucleophile. According the to Hammond postulate, the stability of the determines the rate of its formation. The formation of equal amounts of two enantiomeric products from a single starting material is called A is an electron-rich compound, which donates a pair of electrons to an electron deficient compound, forming a covalent bond.…