Propanoic acid and methyl ethanoate are constitutional isomers. (b) CH3 (c) CH2 OH propanoic acid Show how to distinguish between them by IR spectroscopy. (Use the Appendix.) (a) Which IR bands would one expect for propanoic acid? 1200-1250 cm 1375-1450 cm7 1450-1475 cm 1630-1820 cm 1200-1250 cm -1 -1 -1 -1 1375-1450 cm7 1450-1475 cm 1630-1820 cm 1200-1250 cm 1375-1450 cm Opropanoic acid Omethyl ethanoate -1 Which IR bands would one expect for methyl ethanoate? 1700-1725 cm -1 -1 1450-1475 cm7 1630-1820 cm CH3 methyl ethanoate 0000 1 1700-1725 cm 1735-1800 cm 2720 cm -1 2500-3300 cm 2720 cm -1 Which IR bands are unique to, i.e. not shared between, the two sets? CH3 -1 1735-1800 cm7 2500-3300 cm -1 -1 -1 1700-1725 cm -1 1 1735-1800 cm -1 2720 cm 2500-3300 cm -1 -1 1 (d) If the IR spectrum shows a band at 1465 cm-¹, which isomer is it?
Propanoic acid and methyl ethanoate are constitutional isomers. (b) CH3 (c) CH2 OH propanoic acid Show how to distinguish between them by IR spectroscopy. (Use the Appendix.) (a) Which IR bands would one expect for propanoic acid? 1200-1250 cm 1375-1450 cm7 1450-1475 cm 1630-1820 cm 1200-1250 cm -1 -1 -1 -1 1375-1450 cm7 1450-1475 cm 1630-1820 cm 1200-1250 cm 1375-1450 cm Opropanoic acid Omethyl ethanoate -1 Which IR bands would one expect for methyl ethanoate? 1700-1725 cm -1 -1 1450-1475 cm7 1630-1820 cm CH3 methyl ethanoate 0000 1 1700-1725 cm 1735-1800 cm 2720 cm -1 2500-3300 cm 2720 cm -1 Which IR bands are unique to, i.e. not shared between, the two sets? CH3 -1 1735-1800 cm7 2500-3300 cm -1 -1 -1 1700-1725 cm -1 1 1735-1800 cm -1 2720 cm 2500-3300 cm -1 -1 1 (d) If the IR spectrum shows a band at 1465 cm-¹, which isomer is it?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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