Propane is a gas commonly used to fuel gas grills and camping stoves.  The structure of propane is shown below. Write the balanced chemical equation for the combustion of propane.  Draw out lewis dot structures to represent all molecules of all products and reactants in this reaction.  The number of each molecule should be reflected in the balanced equation.  Calculate the heat of combustion for propane using the bond enthalpies in the table.  1.00 mol of propane is used to roast marshmallows.  It was determined that the amount of energy absorbed by the marshmallows was only 800 kJ.  Explain this observation.

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Propane is a gas commonly used to fuel gas grills and camping stoves.  The structure of propane is shown below.

  1. Write the balanced chemical equation for the combustion of propane. 
  2. Draw out lewis dot structures to represent all molecules of all products and reactants in this reaction.  The number of each molecule should be reflected in the balanced equation. 
  3. Calculate the heat of combustion for propane using the bond enthalpies in the table. 
  4. 1.00 mol of propane is used to roast marshmallows.  It was determined that the amount of energy absorbed by the marshmallows was only 800 kJ.  Explain this observation. 

 

н
H
H
H-
C-
H
н н
H
Propane
Transcribed Image Text:н H H H- C- H н н H Propane
TABLE 8.4 Average Bond Enthalpies (k)/mol)
Single Bonds
C-H
C-C
C-N
C-O
C-F
C-CI
C-Br
C-I
C-S
F-F
413
348
293
358
N-H
N-N
N-O
N-F
N-CI 200
O-H
O-O
O-F
O CI
O-I
391
463
155
163
146
Cl-F 253
201
272
190
203
C-CI 242
485
234
328
N-Br
243
Br-F 237
S-H
S-F
S-CI
339
327
253
Br-CI 218
Br-Br 193
276
240
H-H
436
259
H-F
567
I-CI
I-Br
I-I
H-CI
431
S-Br
218
208
Si-H
Si-Si
Si-C
Si-O
S-S
323
226
301
368
H-Br 366
266
175
H-I
299
151
Multiple Bonds
C=C
C=C
614
N=N
418
495
839
N=N
941
S-O
S-S
615
N=O
607
523
891
799
EN
418
1072
Transcribed Image Text:TABLE 8.4 Average Bond Enthalpies (k)/mol) Single Bonds C-H C-C C-N C-O C-F C-CI C-Br C-I C-S F-F 413 348 293 358 N-H N-N N-O N-F N-CI 200 O-H O-O O-F O CI O-I 391 463 155 163 146 Cl-F 253 201 272 190 203 C-CI 242 485 234 328 N-Br 243 Br-F 237 S-H S-F S-CI 339 327 253 Br-CI 218 Br-Br 193 276 240 H-H 436 259 H-F 567 I-CI I-Br I-I H-CI 431 S-Br 218 208 Si-H Si-Si Si-C Si-O S-S 323 226 301 368 H-Br 366 266 175 H-I 299 151 Multiple Bonds C=C C=C 614 N=N 418 495 839 N=N 941 S-O S-S 615 N=O 607 523 891 799 EN 418 1072
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