The combustion of 0.1556 g benzoic acid increases the temperature of a bomb calorimeter by 2.50°C. Calculate the heat capacity of this calorimeter. (The energy released by combustion of benzoic acid is 26.42 kJ/g.) Heat capacity= kJ/°C A 0.2194-g sample of vanillin (C8H8O3) is then burned in the same calorimeter, and the temperature increases by 3.20°C. What is the energy of combustion per gram of vanillin? Energy = kJ/g Per mole of vanillin? Energy = kJ/mol
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Given:
Mass of benzoic acid = 0.1556 g
Increase in temperature = 2.50 °C
Energy released by combustion = 26.42 kJ /g
Mass of vanillin = 0.2194 g
Increase in temperature 3.20 °C
Ccal =1.78kJ/ °C
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