Problem 1. The following data on osmotic pressure are available for a polymer in dioxane (C4H8O2, p=1.035 g cm³) at 298 K: Mass concentration of polymer Height difference (g = 9.807 m. s²²) c/g-L-¹ h/cm 3.98 5.79 8.05 11.40 1.09 1.76 2.77 4.68 Determine the molar mass of the polymer and the osmotic second virial coefficient (30 points). Are the net interactions between two polymer chains attractive or repulsive (5 point)? Use Excel to make your plot. Submit your plot online (10 points). [Ans: MB=123 kg·mol¹, B =12 m³.mol-¹]
Problem 1. The following data on osmotic pressure are available for a polymer in dioxane (C4H8O2, p=1.035 g cm³) at 298 K: Mass concentration of polymer Height difference (g = 9.807 m. s²²) c/g-L-¹ h/cm 3.98 5.79 8.05 11.40 1.09 1.76 2.77 4.68 Determine the molar mass of the polymer and the osmotic second virial coefficient (30 points). Are the net interactions between two polymer chains attractive or repulsive (5 point)? Use Excel to make your plot. Submit your plot online (10 points). [Ans: MB=123 kg·mol¹, B =12 m³.mol-¹]
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter13: The Chemistry Of Solutes And Solutions
Section: Chapter Questions
Problem 107QRT
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