Problem 1. The following data on osmotic pressure are available for a polymer in dioxane (C4H8O2, p=1.035 g cm³) at 298 K: Mass concentration of polymer Height difference (g = 9.807 m. s²²) c/g-L-¹ h/cm 3.98 5.79 8.05 11.40 1.09 1.76 2.77 4.68 Determine the molar mass of the polymer and the osmotic second virial coefficient (30 points). Are the net interactions between two polymer chains attractive or repulsive (5 point)? Use Excel to make your plot. Submit your plot online (10 points). [Ans: MB=123 kg·mol¹, B =12 m³.mol-¹]

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
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Chapter13: The Chemistry Of Solutes And Solutions
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Problem 1. The following data on osmotic pressure are available for a polymer in dioxane
(C4H8O2, p=1.035 g cm³) at 298 K:
Mass concentration of polymer
Height difference (g = 9.807 m. s²²)
c/g-L-¹
h/cm
3.98
5.79 8.05 11.40
1.09 1.76 2.77 4.68
Determine the molar mass of the polymer and the osmotic second virial coefficient (30
points). Are the net interactions between two polymer chains attractive or repulsive (5
point)? Use Excel to make your plot. Submit your plot online (10 points). [Ans: MB=123
kg·mol¹, B =12 m³.mol-¹]
Transcribed Image Text:Problem 1. The following data on osmotic pressure are available for a polymer in dioxane (C4H8O2, p=1.035 g cm³) at 298 K: Mass concentration of polymer Height difference (g = 9.807 m. s²²) c/g-L-¹ h/cm 3.98 5.79 8.05 11.40 1.09 1.76 2.77 4.68 Determine the molar mass of the polymer and the osmotic second virial coefficient (30 points). Are the net interactions between two polymer chains attractive or repulsive (5 point)? Use Excel to make your plot. Submit your plot online (10 points). [Ans: MB=123 kg·mol¹, B =12 m³.mol-¹]
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