Problem 1: A major assumption in the application of the ideal gas equation of state is that the diameter of the molecules/atoms in a system is significantly shorter than the mean free path. For the two cases below, neglecting contributions from intermolecular forces, determine the validity of the applying ideal gas law. Assume a molecular diameter for ethanol (C¿H;OH) of 0.430 nm and 0.505 nm for 1-butanol (C,H,OH). Case 1: ethanol (5 atm, 900 K) Case 2: 1-butanol (200 atm, 500 K)

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Problem 1: A major assumption in the application of the ideal gas equation of state is that the diameter of
the molecules/atoms in a system is significantly shorter than the mean free path.
For the two cases below, neglecting contributions from intermolecular forces, determine the
validity of the applying ideal gas law. Assume a molecular diameter for ethanol (C,H;OH) of
0.430 nm and 0.505 nm for 1-butanol (C4H,OH).
Case 1: ethanol (5 atm, 900 K)
Case 2: 1-butanol (200 atm, 500 K)
Transcribed Image Text:Problem 1: A major assumption in the application of the ideal gas equation of state is that the diameter of the molecules/atoms in a system is significantly shorter than the mean free path. For the two cases below, neglecting contributions from intermolecular forces, determine the validity of the applying ideal gas law. Assume a molecular diameter for ethanol (C,H;OH) of 0.430 nm and 0.505 nm for 1-butanol (C4H,OH). Case 1: ethanol (5 atm, 900 K) Case 2: 1-butanol (200 atm, 500 K)
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