Prediction of Molecular Structure II When phosphorus reacts with excess chlorine gas, the compound phosphorus pentachlo- ride (PCI3) is formed. In the gaseous and liquid states, this substance consists of PCI5 molecules, but in the solid state it consists of a 1:1 mixture of PCI,+ and PCI, ions. Predict the geometric structures of PCI5, PCI4*, and PCI,¯.
Prediction of Molecular Structure II When phosphorus reacts with excess chlorine gas, the compound phosphorus pentachlo- ride (PCI3) is formed. In the gaseous and liquid states, this substance consists of PCI5 molecules, but in the solid state it consists of a 1:1 mixture of PCI,+ and PCI, ions. Predict the geometric structures of PCI5, PCI4*, and PCI,¯.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Prediction of Molecular Structure II
When phosphorus reacts with excess chlorine gas, the compound phosphorus pentachlo-
ride (PCI3) is formed. In the gaseous and liquid states, this substance consists of PCI5
molecules, but in the solid state it consists of a 1:1 mixture of PCI,+ and PCI, ions.
Predict the geometric structures of PCI5, PCI4*, and PCI,¯.
Transcribed Image Text:Prediction of Molecular Structure III
Because the noble gases have filled s and p valence orbitals, they were not expected to be
chemically reactive. In fact, for many years these elements were called inert gases because
of this supposed inability to form any compounds. However, in the early 1960s several
compounds of krypton, xenon, and radon were synthesized. For example, a team at the
Argonne National Laboratory produced the stable colorless compound xenon tetrafluoride
(XeF4). Predict its structure and whether it has a dipole moment.
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