Mixing SbCl3 and GaCl3 in a 1:1 molar ratio (using liquid sulfur dioxide as solvent) gives a solid ionic compound of empirical formu la GaSbCls. A controversy arises over whether this compou nd is (SbCl2•)(GaC l4 ) or (GaCl2•)(SbC l4").
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Mixing SbCl3 and GaCl3 in a 1:1 molar ratio (using liquid sulfur dioxide as solvent) gives a solid ionic compound of empirical formu la GaSbCls. A controversy arises over whether this compou nd is (SbCl2•)(GaC l4 ) or (GaCl2•)(SbC l4").
- Predict the molecular structure of the two
- It is learned that the cation in the compounds has a bent Basic on this fact, which formulation is more likely to be correct?
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Mult iply charged ions have received growing attention by the scientific community due to their interesting physical properties and their observation in many fields such as plasma chemistry, surface science, but also in interstellar chemistry, where we can find some molecules not readily observe otherwise. In this problem we will use Molecular
Orbital theory to predict the stability of molecules. Consider the diatom ic Ne2 and its cation derivative, Ne2 +, t.Jt'l.-+ ovr1.w
- Draw correlation diagrams for the Remember to proper ly show which MO correlates with each AO.
- Based on MO considerations provide the bond order of these species.
c . The equilibrium distance for Ne2+ is 1. 75 Angstroms.
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The Bond energy of C2(g) is 599 kJ/mo l and for F2 is 154 kJ/mol. Use MO theory to justify the difference.
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