Predict which of the following carbocations will undergo rearrangement. For those that will rearrange, show the rearranged structure. For those that don't rearrange, explain why. +
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- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic steps. Be sure to account for all bond-breaking and bond-making steps. H H y H H ✪ I CH3OH heat CH3OH heat HH H : Br: O CH3OH heat Drawing ArrowsWhen we have discussed the enol-keto tautomerization of ketones in class, the isomerization has been facililated by an acid or base catalyst, with most ketones heavily favoring the carbonyl isomer at equilibrium. However, samples of the ketone below in its pure form (with no acid, base or water present) contain nearly 10% of the enol form! OH -90% -10% From this data, we can infer that the enol isomer of this ketone is particularly stable. Explain the stability of this enol, using terms and ideas that we have discussed in this unit.Complete the mechanism of hydration of alkene below. Please follow curved arrows to predict the resulting structures in each step Step 1 of hydration of 2-methyl-1-propene (Note that the most stable carbocation is formed here) Step 2 of hydration of 2-methyl-1-propene(Note that the most stable carbocation is formed here) Step 3 of hydration of 2-methyl-1-propene
- React each molecule with each of the substrates on the right include step by step reaction also inclue arrows and drawAddition of HBr to which of the attached alkenes will lead to a rearrangement?[Review Topica) Draw a structural formula for the more stable carbocation intermediate formed in the reaction shown. [References) CH;CH2 H C=C HCI H. CH2CH(CH3)2 • You do not have to consider stereochemistry. • Do not include anionic counter-ions, e.g., I", in your answer. • For cases in which carbocations of the same or similar stability are expected, draw all of the structures. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures with + signs from the drop-down menu. C P. opy aste ba 2req = 2req Previous Next Save and Exit APR MacBook Air DII 品留 F4 80 F9 F10 FS F3 & %23 $ %3D 3 4 5 6 8 9 { P E R т Y F G H J K L C V N command oprion -
- 2) Provide a detailed mechanism for the addition reaction shown below. State the regiochemistry and explain why it's unusual. SCH3 HBr Br SCH3 EN Please be sure to include all structures (use line angle notation or perspective diagrams as appropriate to illustrate the stereochemistry of the process), resonance forms, intermediates, transition states, curved arrows, formal charges, or lone pairs as necessary. Please redraw the substrateCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron- pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. 0°• 1 H Drawing Arrows NaOH, H₂O heat :I:0 > H. Na Ⓒ :O:Identify the two diastereomeric hydroboration-oxidation products that can be formed from the following alkene by dragging the product pair to the product bin. Then suggest which product should be the major product or whether they will be formed in equal amounts by dragging the appropriate label to the bin under the products. Note: If one or more labels are incorrectly placed, a single red X will appear on the top left. 1) ВНз, ТHF 2) H-Ог. - ОН он Н Oн Н HI OH Н Он H ОН Н Он H Он Он. Н ОН Он ОН OH major praduct minor product minor product major product approximately equal amountsi
