Predict the phase of water that exists under the following conditions: a) P = 200 kPa, T=110°C b) P = 24,000 kPa, T = 384°C c) P = 0.60 kPa, T = 100°C
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Predict the phase of water that exists under the following conditions:
a) P = 200 kPa, T=110°C
b) P = 24,000 kPa, T = 384°C
c) P = 0.60 kPa, T = 100°C
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- Give correct answerWhen barium carbonate dissociates according to the reaction, Baco; (s) = Bao (s) + CO2 (g) the pressure of CO2 g) in equilibrium with the solid phases is 7.0x10-2 bar at 1400 K and 0.37 bar at 1500 K. Use this information to calculate 4,H°, 4,G° and 4,S° at 298.15 K. You may assume that 4,H° is independent of temperature.Hydrogen gas can be produced from the reaction of graphite and steam according to the following reaction: C(s, graphite) + H2O(g) - CO(g) + H2(g) K = 2.77x10-4 at 650 K 2.67 bar of gaseous H20 and excess graphite are added to a sealed container and then heated to 650 K. What is the partial pressure of gaseous H2, in units of bar, when the system reaches dynamic equilibrium?
- A handbook lists the normal boiling point of isooctane, a gasoline component, as 99.2ºC and its enthalpy of vaporization as 35.76 kJ mol-1. Calculate the vapor pressure of isooctane at 25ºC.Hydrogen gas can be produced from the reaction of graphite and steam according to the following reaction: C(s, graphite) + H20(g) = CO(g) + H2(g) K= 2.77x10-4 at 650 K 6.27 bar of gaseous H20 and excess graphite are added to a sealed container and then heated to 650 K. What is the partial pressure of gaseous H2, in units of bar, when the system reaches dynamic equilibrium? Your Answer: Answer Answer unitsBinary phase diagram of an aluminum – silicon mixture Data: Tmelt(Al) = 660 °C Tmelt(Si) = 1412 °C Silicon forms an alloy in the liquid state (total miscibility) with aluminum. The two metals are not miscible in the solid state. The temperature of solidification of the Si-Al alloy is minimal at 580 °C for a mass fraction of silicon wsj equal to 0.125. What are the phases in presence when the system is in equilibrium in the following conditions: A C D wSi 0.05 0.125 0.5 0 (°C) 700 600 550 700
- (a) Identify the major phases (ice, water, vapor) on the unary phase diagram of H2O below.The vapor pressure of benzene between 285 K and 310 K fits the expression log P = 10.086 – 1780.172 (1/T) (P in Pa; T in K)Calculate the molar enthalpy of vaporization and the normal boiling point of benzene. Compare the normal boiling point with that of the boiling point obtained from Trouton’s RuleConsider a liquid mixture of CHCl3 (component A) and CH₂Cl₂ (component B) with XB = 0.750. For each of the pure substances, one can find expressions relating their vapor pressure to temperature in the NIST Webbook: 2839.38 (T - 40.953) 3055.57 (T - 20.474) (a) Assuming that the solution is ideal, determine its total vapor pressure (in bars) at 300 K and the mole fractions of the two components in the vapor phase. Assume that the vapor behaves as an ideal gas. In In PA 1 bar PB 1 bar = 9.6886 - = 10.4466- (b) The actual total vapor pressure of the solution is observed to be 0.492 bar, and the mole fraction of component B in the vapor phase is yB = 0.900. Use this information, along with the results of part (a), to calculate the activity and the activity coefficient (based on a Raoult's Law standard state) of component A (chloroform) for this mixture.
- Consider propylene at boiling conditions (a) What is its boiling temperature at 101.3 kPa? 200 kPa? 500 kPa? 2500 kPa? (b) What is the boiling pressure of propylene at 70° and 20° C?At 25 °C, the equilibrium partial pressures for the reaction 3 A(g) + 2 B(g) = C(g) + 2 D(g) were found to be PA 5.61 atm, PB = 4.31 atm, Pc = 5.66 atm, and P = 5.84 a %3D %3D What is the standard change in Gibbs free energy of this reaction at 25 °C? kJ AGixn molBinary phase diagram of an aluminum – silicon mixture Data: Tmelt(Al) = 660 °C Tmelt(Si) = 1412 °C Silicon forms an alloy in the liquid state (total miscibility) with aluminum. The two metals are not miscible in the solid state. The temperature of solidification of the Si-Al alloy is minimal at 580 °C for a mass fraction of silicon wSj equal to 0.125. Give a representation of the liquid-solid diagram T=f(wSi) that takes into account these data. One will assimilate liquidus curves to straight lines.
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