CO₂ has a positive slope on the melting (fusion) curve. Using the questions below as a guide, show that CO₂ expands upon melting, without employing the Clausius-Clapeyron equation. (i) (ii) (iii) Sketch the specific Gibbs free energies of both phases as a function of pressure using the p - T phase diagram. Use derivatives of the specific Gibbs free energies to obtain the sketch. Sketch the specific volumes of both phases as a function of pressure. Explain how you obtained the sketch of the specific volumes, hence show that CO₂ expands upon melting.
CO₂ has a positive slope on the melting (fusion) curve. Using the questions below as a guide, show that CO₂ expands upon melting, without employing the Clausius-Clapeyron equation. (i) (ii) (iii) Sketch the specific Gibbs free energies of both phases as a function of pressure using the p - T phase diagram. Use derivatives of the specific Gibbs free energies to obtain the sketch. Sketch the specific volumes of both phases as a function of pressure. Explain how you obtained the sketch of the specific volumes, hence show that CO₂ expands upon melting.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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![CO₂ has a positive slope on the melting (fusion) curve. Using the questions below as a guide, show
that CO₂ expands upon melting, without employing the Clausius-Clapeyron equation.
(i)
(ii)
(iii)
Sketch the specific Gibbs free energies of both phases as a function of pressure using the
p - T phase diagram. Use derivatives of the specific Gibbs free energies to obtain the
sketch.
Sketch the specific volumes of both phases as a function of pressure.
Explain how you obtained the sketch of the specific volumes, hence show that CO₂ expands
upon melting.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4b13f30d-f866-4da6-8a9a-78f338e48b5d%2F41fcbb33-43ea-459d-873a-ff81f90f4edd%2Fng5x5yh_processed.png&w=3840&q=75)
Transcribed Image Text:CO₂ has a positive slope on the melting (fusion) curve. Using the questions below as a guide, show
that CO₂ expands upon melting, without employing the Clausius-Clapeyron equation.
(i)
(ii)
(iii)
Sketch the specific Gibbs free energies of both phases as a function of pressure using the
p - T phase diagram. Use derivatives of the specific Gibbs free energies to obtain the
sketch.
Sketch the specific volumes of both phases as a function of pressure.
Explain how you obtained the sketch of the specific volumes, hence show that CO₂ expands
upon melting.
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