Ph i-Pr 1. toluene, heat Me. 2. H2C-PPH3 (e) Me Me cat. H* Me OPP (f) 1. NH2 MeOH, H* 2. xylenes, heat 3. F3C cat. Pd(PPh,)., KOIBU Br

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(d)
Ph
i-Pr
1. toluene, heat
Me
2. O 0
H2C-PPH3
(e)
Me
Me
cat. H+
Me
OPP
(f)
NH2
MEOH, H*
2. xylenes, heat
3.
F3C
cat. Pd(PPh,),, KOIBU
Br
Transcribed Image Text:(d) Ph i-Pr 1. toluene, heat Me 2. O 0 H2C-PPH3 (e) Me Me cat. H+ Me OPP (f) NH2 MEOH, H* 2. xylenes, heat 3. F3C cat. Pd(PPh,),, KOIBU Br
(a)
NH2
N.
AcO
OAc
H.
AcO
OAc
(b)
1. cat. H*
но
2.
CI, DMSO
CI
NE13, CH2Cl2, -78 °C
(c)
1. Br
OH
KH, 18-c-6, THF
2. xylenes, heat
3. cat.
PCY3
CH,Cl2
Ci-Ru
Ph
PCy
Transcribed Image Text:(a) NH2 N. AcO OAc H. AcO OAc (b) 1. cat. H* но 2. CI, DMSO CI NE13, CH2Cl2, -78 °C (c) 1. Br OH KH, 18-c-6, THF 2. xylenes, heat 3. cat. PCY3 CH,Cl2 Ci-Ru Ph PCy
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