Part A When a 0.240-g sample of benzoic acid is combusted in a bomb calorimeter, the temperature rises 1.641 °C. When a 0.275-g sample of caffeine, Cg H10O2N4, is burned, the temperature rises 1.549 °C. Using the value 26.38 kJ/g for the heat of combustion of benzoic acid, calculate the heat of combustion per mole of caffeine at constant volume.

Part A When a 0.240-g sample of benzoic acid is combusted in a bomb calorimeter, the temperature rises 1.641 °C. When a 0.275-g sample of caffeine, Cg H10O2N4, is burned, the temperature rises 1.549 °C. Using the value 26.38 kJ/g for the heat of combustion of benzoic acid, calculate the heat of combustion per mole of caffeine at constant volume.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

A 1.200 g sample of ZnCO3 (s) dissolved in 40.0 mL of a dilute HCl solution (density = 1.10 g/mL) in a coffee cup calorimeter, producing CO2 (g), liquid water and ZnCl2 (aq). The temperature of the solution changes from 24.32 oC to 25.49 oC. The resulting solution has a specific heat of 4.18 J/goC. What would be a balanced equation for this reaction.
12. When 1.025 g of naphthalene (C10H8) is burned in a bomb calorimeter, the temperature rises from 24.25°C to 32.33°C. Find AEren for combustion of naphthalene in kJ/mol. Heat capacity of the calorimeter is 5.11 kJ/°C. 13. When 10.0 g of phosphorus is burned in oxygen gas to form solid P4O10, enough heat is generated to raise the temperature of 2960 g of water from 18.0°C to 38.0°C. Calculate the enthalpy of formation of solid P4O10 under these conditions.
A certain chemical reaction releases 269. kJ of heat energy per mole of reactant consumed. Suppose some moles of the reactant are put into a calorimeter (a device for measuring heat flow). It takes 3.21 J of heat energy to raise the temperature of this calorimeter by 1 °C. Now the reaction is run until all the reactant is gone, and the temperature of the calorimeter is found to rise by 5.0 °C. How would you calculate the number of moles of reactant that were consumed? Set the math up. But don't do any of it. Just leave your answer as a math expression. Also, be sure your answer includes all the correct unit symbols. moles consumed = x10 010 X Ś
When 1.836 grams of sucrose (Molar mass 342.3 g/mol) is burned in a bomb calorimeter, the temperature of the calorimeter increases from 22.41°C to 26.63°C. If the heat capacity of the calorimeter is 4.900 kJ/°C, what is the heat of combustion of sucrose?
when 11.0 g naoh is dissolved in 100.0 g of water in a coffee-cup calorimeter, the temperature rises from 25.22c to 48.00c. what is the enthalpy change?
When pure sulfuric acid is dissolved in water, heat is evolved. 10.65 g of pure sulfuric acid at 20.00 °C was added to a calorimeter containing 300 g of water at 20.00 °C. The temperature of the solution increased to 26.35 °C. If the specific heat of the mixture is 4.184 Jg1°C1, the density of water is 1 g/mL, and the heat capacity of the calorimeter is ignored, what is the heat evolved per mole of sulfuric acid? a. -83.2 kJ O b. -73.6 kJ O C. -76.0 kJ d. -80.8 kJ e. -78.4 kJ
calculate the heat (in J) of the reaction if 50.0 mL of HCl is added to 50.0 mL of NaOH in a coffee-cup calorimeter. The initial temperature for both solutions is 23.2oC. At the end of the reaction after the data is graphed, the final temperature is determined to be 38.5oC.
When 6.54 grams of Zn is placed in 500.0 mL of 1.00 M CuSO4(aq) in a coffee cup calorimeter, it reacts completely to displace copper. The temperature of the solution rises from 20.0˚C to 30.4˚C. Assume the coffee cup itself gains no heat and that the solution has the same density (1.00 g/mL) and specific heat (4.184 J/g˚C) as pure water. (a) How much heat does the solution gain during this reaction? (in J)
The burning of 28g of vegetable cause the temperature of 58.18 g of water in a soda can calorimeter to increase from 21.5°C to 28.1 Calculate the amount of heat absorbed by the water using the specific heat of water at 4.18 J/gºC.
At constant volume, the heat of combustion of a particular compound, compound A, is −3046.0 kJ/mol.−3046.0 kJ/mol. When 1.753 g1.753 g of compound A (molar mass =112.07 g/mol)=112.07 g/mol) is burned in a bomb calorimeter, the temperature of the calorimeter (including its contents) rose by 6.475 ∘C.6.475 ∘C. What is the heat capacity (calorimeter constant) of the calorimeter? Suppose a 3.771 g3.771 g sample of a second compound, compound B, is combusted in the same calorimeter, and the temperature rises from 25.65 ∘C25.65 ∘C to 29.76 ∘C.29.76 ∘C. What is the heat of combustion per gram of compound B?
When a student mixes 50 mL of 1.0 M HCl and 50 mL of 1.0 M NaOH in a coffee-cup calorimeter, the temperature of the resultant solution increases from 21.0°C to 27.5°C. calculate the enthalpy change for the reaction in kJ/mol HCl, assuming that the calorimeter loses only a negligible quantity of heat, that the total volume of the solution is 100 mL, that its density is 1.0 g/mL, and that its specific heat is 4.18 J/g•K. O -27000 J O 54 kJ O 2.7 kJ O -54 kJ
75.0 mL of 1.80 M CuSO 4 solution is mixed with 150 mL of 1.80 M NAOH solution in a coffee cup calorimeter of negligible heat capacity. If the initial temperature of the two solutions are both 21.0 degrees C, and the final temperature of the mixed solution is 27.1, how much heat was released by the reaction? Assume density of solution d is 1.00 g/mL and that the solution has the same specific heat as water. The thermochemical equation is: CuSO4 (ag) + 2NAOH (ag) --> Cu(OH)2 (s) + Na SO4 (ag) AH xn = - 42.3 kJ/mol rxn Hint: no limiting reagent, substances are presented in correct molar ratios. O 6180 J O 9270 J O 3120 J O 5740 J O 9300 J O 1250 J O 6230 J O 3380 J