P1) What is the correct IUPAC name of the compound below? Br OH otions is Fischer A) 3-(2-bromopropyl)-6,6-dimethylheptan-2-ol B) 5-bromo-3-(3,3-dimethylbutyl)hexan-2-ol C) 5-(2-bromopropyl)-2,2-dimethylheptan-6-ol D) 7-bromo-5-(1-hydroxyethyl)-2,2-dimethyloctane 22) What would be the alcohol product if MeMgBr/ether & H3O* are ac

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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21) What is the correct IUPAC name of the compound below?
Br
OH
ctions is Fische
A) 3-(2-bromopropyl)-6,6-dimethylheptan-2-ol
B) 5-bromo-3-(3,3-dimethylbutyl)hexan-2-ol
C) 5-(2-bromopropyl)-2,2-dimethylheptan-6-ol
D) 7-bromo-5-(1-hydroxyethyl)-2,2-dimethyloctane
22) What would be the alcohol product if MeMgBr/ether & H;O* are added to 3
3
(1) p-ethyl benzoic acid, (ii) p-nitro benzoic acid, (iii) p-cyano benzoit at
(iii)
30) Show an increase in the oruUI
(c) (i) < (ii) < (iii) (d) (ii
Transcribed Image Text:21) What is the correct IUPAC name of the compound below? Br OH ctions is Fische A) 3-(2-bromopropyl)-6,6-dimethylheptan-2-ol B) 5-bromo-3-(3,3-dimethylbutyl)hexan-2-ol C) 5-(2-bromopropyl)-2,2-dimethylheptan-6-ol D) 7-bromo-5-(1-hydroxyethyl)-2,2-dimethyloctane 22) What would be the alcohol product if MeMgBr/ether & H;O* are added to 3 3 (1) p-ethyl benzoic acid, (ii) p-nitro benzoic acid, (iii) p-cyano benzoit at (iii) 30) Show an increase in the oruUI (c) (i) < (ii) < (iii) (d) (ii
D) 8
E) 5
18) Deduce the identity of the following compound from the 1H NMR data given.
C3H100: ô 3.4 (3H, singlet), 4.5 (2H, singlet), 7.2 (5H, apparent singlet) (ppm)
(а) Ph-CH-CH2ОН
(b) Ph-CH2-O-CH3
(c) p-CH3-Ph-O-CH3
(d) p-CH3CH2-Ph-OH
19)
Deduce the identity of the following compound from the 13C NMR data given.
C9H12: 8 21.3 (quartet), 127.2 (doublet), 138.0 (singlet) (ppm)
(a) 1,3,5-trimethyl benzene
(d) 1-ethyl-3-methyl benzene
(b) 1-ethyl-4-methyl benzene
(c) 1,2,4-trimethyl benzene
20) Which of the following reagents would be suitable for making "ethyl-benzene" from
"acetophenone" (i.e. via a reduction process)?
(a) Zn/HCl
(b) NHNH>/KOН
(c) LAH/H;O* (d) NABH4/MEOH
21) What is the correct IUPAC name of the compound below?
Br
Transcribed Image Text:D) 8 E) 5 18) Deduce the identity of the following compound from the 1H NMR data given. C3H100: ô 3.4 (3H, singlet), 4.5 (2H, singlet), 7.2 (5H, apparent singlet) (ppm) (а) Ph-CH-CH2ОН (b) Ph-CH2-O-CH3 (c) p-CH3-Ph-O-CH3 (d) p-CH3CH2-Ph-OH 19) Deduce the identity of the following compound from the 13C NMR data given. C9H12: 8 21.3 (quartet), 127.2 (doublet), 138.0 (singlet) (ppm) (a) 1,3,5-trimethyl benzene (d) 1-ethyl-3-methyl benzene (b) 1-ethyl-4-methyl benzene (c) 1,2,4-trimethyl benzene 20) Which of the following reagents would be suitable for making "ethyl-benzene" from "acetophenone" (i.e. via a reduction process)? (a) Zn/HCl (b) NHNH>/KOН (c) LAH/H;O* (d) NABH4/MEOH 21) What is the correct IUPAC name of the compound below? Br
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