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OTs - (strong base) В Doubling [B] doubles rate of rxn.

OTs - (strong base) В Doubling [B] doubles rate of rxn.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Given the information below, write out a reasonable mechanism for the reaction. Where not provided, also fill in the major product(s) of the reaction:

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### Reaction Overview: **Reactant:** - A benzene ring with an OTs (tosylate) group attached, indicating it as the starting material. **Reagent:** - A strong base, denoted as \( \text{B}^- \). ### Reaction Process: - The reaction proceeds with the strong base (\( \text{B}^- \)) attacking the substrate with the tosylate group, implying a deprotonation or substitution/elimination mechanism. ### Rate Relationship: - The note "Doubling [\( \text{B}^- \)] doubles rate of reaction" suggests that the reaction rate is directly proportional to the concentration of the base. This indicates that the reaction follows first-order kinetics with respect to the base, \( \text{B}^- \). This reaction is typically studied in organic chemistry to understand substitution and elimination mechanisms, particularly those involving leaving groups like tosylates and the role of bases.
Transcribed Image Text:### Reaction Overview: **Reactant:** - A benzene ring with an OTs (tosylate) group attached, indicating it as the starting material. **Reagent:** - A strong base, denoted as \( \text{B}^- \). ### Reaction Process: - The reaction proceeds with the strong base (\( \text{B}^- \)) attacking the substrate with the tosylate group, implying a deprotonation or substitution/elimination mechanism. ### Rate Relationship: - The note "Doubling [\( \text{B}^- \)] doubles rate of reaction" suggests that the reaction rate is directly proportional to the concentration of the base. This indicates that the reaction follows first-order kinetics with respect to the base, \( \text{B}^- \). This reaction is typically studied in organic chemistry to understand substitution and elimination mechanisms, particularly those involving leaving groups like tosylates and the role of bases.
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