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OsO4 H₂O₂ g (viii) T MCPBA CH₂Cl2 b)

OsO4 H₂O₂ g (viii) T MCPBA CH₂Cl2 b)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(vii) ix a) a) O c) OSO4 H₂O₂ D₂ Ni b) b) (viii) (x) a) a) c) MCPBA CH₂Cl2 b) 1) Hg(OAc)2, H₂O 2) NaBH4 c) b)
Transcribed Image Text:(vii) ix a) a) O c) OSO4 H₂O₂ D₂ Ni b) b) (viii) (x) a) a) c) MCPBA CH₂Cl2 b) 1) Hg(OAc)2, H₂O 2) NaBH4 c) b)
a) H₂ Pd C-C -H and -H + A-B For the following reagents, indicate the following: a) what is added accross the double bond; b) is the addition stereoselective/stereospecific? If yes, do A and B add syn or anti?; c) draw the product, with relevant stereochemistry, when the reagent system shown is reacted with 1-methylcyclopentene. The answer to the first reagent system is shown below. (i) b) yes, syn addition | | -C-C- (achiral, stereochem. not observable) | I A B (ii) a) 1) 9-BBN 2) H₂O2, NaOH(aq) b)
Transcribed Image Text:a) H₂ Pd C-C -H and -H + A-B For the following reagents, indicate the following: a) what is added accross the double bond; b) is the addition stereoselective/stereospecific? If yes, do A and B add syn or anti?; c) draw the product, with relevant stereochemistry, when the reagent system shown is reacted with 1-methylcyclopentene. The answer to the first reagent system is shown below. (i) b) yes, syn addition | | -C-C- (achiral, stereochem. not observable) | I A B (ii) a) 1) 9-BBN 2) H₂O2, NaOH(aq) b)
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