Orbital Energies (eV) C 2s = -19.43 C 2p = -10.66 S 3s = -22.71 S 3p = -11.62 s=c=S %3D Dan (yz) Ay -1 -1 -1 -1 R -1 -1 -1 -1 R, -1 -1 -1 -1 R. A -1 -1 -1 -1 -1 -1 -1 -1 In Dzh symmetry, what are the Mulliken symbols for the atomic orbital entral carbon atom?:
Carbohydrates
Carbohydrates are the organic compounds that are obtained in foods and living matters in the shape of sugars, cellulose, and starch. The general formula of carbohydrates is Cn(H2O)2. The ratio of H and O present in carbohydrates is identical to water.
Starch
Starch is a polysaccharide carbohydrate that belongs to the category of polysaccharide carbohydrates.
Mutarotation
The rotation of a particular structure of the chiral compound because of the epimerization is called mutarotation. It is the repercussion of the ring chain tautomerism. In terms of glucose, this can be defined as the modification in the equilibrium of the α- and β- glucose anomers upon its dissolution in the solvent water. This process is usually seen in the chemistry of carbohydrates.
L Sugar
A chemical compound that is represented with a molecular formula C6H12O6 is called L-(-) sugar. At the carbon’s 5th position, the hydroxyl group is placed to the compound’s left and therefore the sugar is represented as L(-)-sugar. It is capable of rotating the polarized light’s plane in the direction anticlockwise. L isomers are one of the 2 isomers formed by the configurational stereochemistry of the carbohydrates.
Answer the following questions?
![Question 1
system as shown. The poinu group of CS2 can be approximated as Dzh. For this problem.
all orbitals on carbon and sulfur can form bonding interactions.
Consider the linear CS2 molecule below with the coordinate
Orbital Energies (eV)
C 2s = -19.43
C 2p = -10.66
S 3s = -22.71
S 3p = -11.62
s=c=s
Dan
Ca (2)
lyz)
Ay
1.
Big
1
-1
-1
1
-1
R
-1
xy
1
-1
1
-1
-1
-1
Ry
-1
-1
1
-1
-1
R.
ye
A.
1
1
-1
-1
-1
-1
-1
-1
-1
-1
Ba
Part A
of the central carbon atom?:
In Dzh symmetry, what are the Mulliken symbols for the atomic orbital
Pz =
Py =
Pz =
Part B
Cetermine the SALCS for all of the sulfur s- and p-orbitals. For full
credit, derive the irreducible representations, draw and write the expression for the sulfur
SALCS. Use additional pages if needed.
Part C
Sketch a Molecular Orbital Diagram for CS2 based on the SALCS
generated in part B. Fill the diagram with the appropriate number of electrons and draw
all bonding, non-bonding and anti-bonding molecular orbitals. Also indicate the
symmetry of each molecular orbital. Be sure to draw pictures of the molecular orbitals
(i.e. AO's + SALCS) to accompany their placement in the diagram.
Part D
discussion on CO2, please briefly describe the expected differences in reactivity between
CO2 and CS2. Please use the language of molecular orbital theory and orbital energies
when writing your response
Based on the MO diagram generated in Part C and the lecture](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F3441c870-6ffd-4dcc-93b8-2f0c4f6bfe99%2F5e411485-3fe5-4128-82f8-f48552b64f40%2Fl9ghdco_processed.png&w=3840&q=75)
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