Operating Wavelength : 462.8 nm Preparation of Standard Calibration Curve of [FeSCN]2+ Sample Number Absorbance Final Concentration of [FeSCN]2+(M) A 0.058 4.0E-5 B 0.174 8.0E-5 C 0.455 1.2E-4 D 0.740 1.6E-4 E 0.833 2.0E-4 Determination of [FeSCN]2+ in Equilibrium Mixtures Sample Number Absorbance 1 0.190 2 0.272 3 0.388 4 0.441 Determination of [FeSCN]2+ in equilibrium mixtures For Sample #1: the initial concentration of Fe3+ 0.0010 M the equilibrium concentration of Fe3+. 9.54×10-4 M the initial concentration of HSCN. 4.00×10-4 M the equilibrium concentration of HSCN. 3.54×10-4 M Calculate Keq for sample 1. ?

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Operating Wavelength : 462.8 nm

Preparation of Standard Calibration Curve of [FeSCN]2+

Sample Number Absorbance Final Concentration of [FeSCN]2+(M)
A 0.058 4.0E-5
B 0.174 8.0E-5
C 0.455 1.2E-4
D 0.740 1.6E-4
E 0.833 2.0E-4

Determination of [FeSCN]2+ in Equilibrium Mixtures

Sample Number Absorbance
1 0.190
2 0.272
3 0.388
4 0.441

Determination of [FeSCN]2+ in equilibrium mixtures

For Sample #1:

the initial concentration of Fe3+

0.0010 M

the equilibrium concentration of Fe3+.

9.54×10-4 M

the initial concentration of HSCN.

4.00×10-4 M

the equilibrium concentration of HSCN.

3.54×10-4 M

Calculate Keq for sample 1. ?

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