One of the chair conformers of cis-1,3-dimethylcyclohexane is 5.4 kcal/molkcal/mol (23 kJ/molkJ/mol) less stable than the other. How much steric strain does a 1,3-diaxial interaction between two methyl groups introduce into the conformer?

One of the chair conformers of cis-1,3-dimethylcyclohexane is 5.4 kcal/molkcal/mol (23 kJ/molkJ/mol) less stable than the other. How much steric strain does a 1,3-diaxial interaction between two methyl groups introduce into the conformer?

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry

Section4.SE: Something Extra

Problem 55AP: myo-Inositol, one of the isomers of 1,2,3,4,5,6-hexahydroxycyclohexane, acts as a growth factor in...

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Question

One of the chair conformers of cis-1,3-dimethylcyclohexane is 5.4 kcal/molkcal/mol (23 kJ/molkJ/mol) less stable than the other. How much steric strain does a 1,3-diaxial interaction between two methyl groups introduce into the conformer?

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