1. (20 pts.) For each of the following transition metal complexes, give the followinginformation:• correct name of the complex or compound based on the complete formula shown⚫ charge of the transition metal•the number of valence d electrons in the transition metal⚫ the most likely molecular geometry of the metal complexwhether the complex obeys the 18-electron rule.Use the space below the table and additional pages for work, calculations, etc.Complex orCompoundK2[C0C14][Cr(H₂O)sBr]²+Ir(NH3)3I3Ru(bipy)2(SCN)2[Pt(phen)(NO)]³+[Sn(acac)3] NO3NameMetalChargeMetal delectronsMolecularObeys 18-electronGeometryrule?

1. K₂[CoCl₄]Name: Potassium tetrachlorocobaltate(II)Metal Charge Calculation:Potassium (K⁺)…

Answered: 1. (20 pts.) For each of the following…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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In the following blanks, write the chemical formula of the named coordination compounds. Use the proper case for the symbol of each atom/ligand and normal numbers, no subscripts or superscripts. Observe proper spacing and use of parenthesis and brackets.
In the following blanks, write the chemical formula of the named coordination compounds. Use the proper case for the symbol of each atom/ligand and normal numbers, no subscripts or superscripts. Observe proper spacing and use of parenthesis and brackets.
Which of the following statements is/are TRUE about magnetism in coordination compounds? 1. d5-metal ion centers will always produce paramagnetic complexes II. d6-metal ion centers will always produce paramagnetic complexes Ill. d4-metal ion centers will always produce diamagnetic square-planar complexes
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The picture below shows one type of bonding interactions between the central metal and surrounding ligands in an octahedral complex. What type of bonding interaction is shown? nonbonding
Among the complex ions formed by M³* (M is a transition metal in 3d block) are the following: [M(H20).J³*, [M(NH;)6]³*, and [MF6]*. These ions have the following 9 observed colors (listed in arbitrary order): yellow-orange, green, and blue. Match each complex with its color. Explain.
Organometallics A. For the following metal complexes indicate: 1) the metal oxidation state, il) the d- electron count, iii) the valence electron count for the complex, iv) the expected metal geometry, and v) draw the complex. (NB: A periodic table is provided on the last page) [Ru(CH)C₂1₂ VO(acac), Oxidation State: +2 +4 d electrons Valence e Geometry Structure [( dppe )Co(CH) [(CH)Y(H)Phol, Oxidation State: d electrons Valence e Geometry Structure 6 5 5
Write out structure representations for all isomers of the following complexes: (c) Pd(en)(SCN)2 (include linkage isomers)
4. For each of the following transition metal complex ions (a) [FeBr2(OH)(NO3)]¹- (b) [RhF3(SCN)3]4- (c) [TiBr4]³- (i) Draw the structure of the transition metal complex ion. Show the charge on the complex in your structure. Give the oxidation state of the metal. State whether the complex is high spin or low spin or not applicable. Provide reasons for your answer. (iv) Draw the arrangement of d-electrons in the ground state. Label the orbital sets. (v) Calculate the LFSE (in units of Ao or AT) for each complex. (ii) (iii)
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Question 1 Consider the following metal ion d-electron configuration and crystal field in octahedral complexes: (i) dº strong field (ii) d³ weak field; (iii) dº weak field; (v) dº strong field. d) Correlate the above metal ion d-electron configuration and crystal field splitting with the following complexes: [Co(CN)c]* ; [Fe(H2O)cJ**; [Fe(CN)«J³; [Co(H2O)6J*.
Consider the coordination complex [Cr(OH₂)3C13] Br3 Identify the ligands by name (include the word "ion" at the end for all ions): What is the charge on the coordination complex? Enter the sign then the numeric value (+2, -2, etc.) What is the oxidation state of the Cr ion? Enter the sign then the numeric value (+2, -2, etc.) What is the coordination number for the complex ion? Enter your answer as a number.

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