On a winter day, you turn on your furnace and the temperature of the air inside your home increases. Assume your home has the normal amount of leakage between inside air and outside air. Is the number of moles of air in your room at the higher temperature (a) larger than before, (b) smallerthan before, or (c) the same as before?

A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P21.65). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state, (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally, (f) Find Q, W, and Eint for each of the processes, (g) For the whole cycle A B C A, find Q, W, and Eint.

A cylinder is closed at both ends and has insulating EZZ3 walls. It is divided into two compartments by an insulating piston that is perpendicular to the axis of the cylinder as shown in Figure P21.75a. Each compartment contains 1.00 mol of oxygen that behaves as an ideal gas with = 1.40. Initially, the two compartments haw equal volumes and their temperatures are 550 K and 250 K. The piston is then allowed to move slowly parallel to the axis of the cylinder until it comes to rest at an equilibrium position (Fig. P2l.75b). Find the final temperatures in the two compartments.

A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P17.68). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state. (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally. (f) Find Q, W, and Eint for each of the processes. (g) For the whole cycle A B C A, find Q, W, and Eint. Figure P17.68

An ideal gas initially at 300 K undergoes an isobaric expansion at 2.50 kPa. If the volume increases from 1.00 m3 to 3.00 m3 and 12.5 kJ is transferred to the gas by heat, what are (a) the change in its internal energy and (b) its final temperature?

In Figure P19.22, the change in internal energy of a gas that is taken from A to C along the blue path is +800 J. The work done on the gas along the red path ABC is 500 J. (a) How much energy must be added to the system by heat as it goes from A through B to C? (b) If the pressure at point A is five times that of point C, what is the work done on the system in going from C to D? Figure P19.22 (c) What is the energy exchanged with the surroundings by heat as the gas goes from C to A along the green path? (d) If the change in internal energy in going from point D to point A is +500 J, how much energy must be added to the system by heat as it goes from point C to point D?

A gas in a cylindrical closed container is adiabatically and quasi-statically expanded from a state A (3 MPa, 2 L) to a state B with volume of 6 L along the path 1.8pV= constant. (a) Plot the path in the pV plane. (b) Find the amount of work done by the gas and the change in the internal energy of the gas during the process.

Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANS

An aluminum rod 0.500 m in length and with a cross sectional area of 2.50 cm2 is inserted into a thermally insulated vessel containing liquid helium at 4.20 K. The rod is initially at 3(H) K. (a) If one-halt of the rod is inserted into the helium, how many liters of helium boil off by the time the inserted half cools to 4.20 K? Assume the upper half does not yet cool, (b) If the circular surface of the upper end of the rod is maintained at 300 K. what is the approximate boil-off rate of liquid helium in liters per second after the lower half has reached 4.20 K? (Aluminum has thermal conductivity of 3 100 YV/m K at 4.20 K; ignore its temperature variation. The density of liquid helium is 125 kg/m3.)

Fifteen identical particles have various speeds: one has a speed of 2.00 m/s, two have speeds of 3.00 m/s, three have speeds of 5.00 m/s, four have speeds of 7.00 m/s, three have speeds of 9.00 m/s, and two have speeds of 12.0 m/s. Find (a) the average speed, (b) the rms speed, and (c) the most probable speed of these particles.